fluorine azide

Base Information

• Chemical Name: fluorine azide
• CAS No.: 14986-60-8
• Molecular Formula: FN3
• Molecular Weight: 61.0185
• Mol file: 14986-60-8.mol

Synonyms:Fluorineazide; Fluorine nitride (FN3); Nitrogen fluoride (N3F)

Chemical Property of fluorine azide

Chemical Property:

• PSA: 49.75000
• LogP: 0.63396

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of fluorine azide

There total 7 articles about fluorine azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogen azide (7782-79-8) + fluorine (7782-41-4) → ammonium fluoride + nitrogen trifluoride (7783-54-2) + dinitrogen difluoride (10578-16-2) + fluoroazide (14986-60-8) + nitrogen (7727-37-9)

Guidance literature:

In neat (no solvent); a mixt. of a small excess of F2 and HN3 dild. with N2 is passed through a spiral tube of copper into two cold traps (the first cooled with aceton/CO2, the second with liq. air);; ppt. in the second cold trap; fractional distn. (explosion possible);;

Reference yield:

hydrogen azide (7782-79-8) + fluorine (7782-41-4) → ammonium fluoride + fluoroazide (14986-60-8) + nitrogen (7727-37-9)

Guidance literature:

In neat (no solvent); react. of F2 and liq. HN3 to gaseous N3F that is partially solved in HN3; explosion after a short time;;

DOI:10.1021/ja01204a053

Reference yield:

hydrogen azide (7782-79-8) + fluorine (7782-41-4) → fluoroazide (14986-60-8)

Guidance literature:

In neat (no solvent); byproducts: HF; mixing of HN3/N2 with F2/N2 (coiled copper tube), caution (inside blastshield); sepn. of HF (NaF trap); detn. by IR, UV spectroscopy;

DOI:10.1021/j100400a038

upstream raw materials:

fluorine

N₅⁽¹⁺⁾*SbF₆^(1-)=(N₅)⁽¹⁺⁾[SbF₆]^(1-)

cesium fluoride

N₅⁽¹⁺⁾*AsF₆^(1-)=[N₅]⁽¹⁺⁾[AsF₆]^(1-)

Downstream raw materials:

nitrogen monofluoride

nitrogen

dinitrogen difluoride

fluoride

Refernces

• 1、 Benard, D. J.,Winker, B. K.,Seder, T. A.,Cohn, R. H.. "Production of NF(a1Δ) by Dissociation of Fluorine Azide". . p. 4790 - 4796. Retrieved 2007/10/02.
• 2、 Patel, D.,Pritt, A. T.,Benard, D. J.. "Photolysis of FN3 at 193 nm". . p. 1931 - 1934. Retrieved 2007/10/02.