cyclohexylazanium;N-cyclohexylcarbamate

Base Information

• Chemical Name: cyclohexylazanium;N-cyclohexylcarbamate
• CAS No.: 20190-03-8
• Molecular Formula: C13H26N2O2
• Molecular Weight: 242.362
• Hs Code.: 2924299090
• Mol file: 20190-03-8.mol

Synonyms:SCHEMBL974699

Chemical Property of cyclohexylazanium;N-cyclohexylcarbamate

Chemical Property:

• Vapor Pressure: 2.42E-07mmHg at 25°C
• Melting Point: 112-113 °C
• Boiling Point: 395°Cat760mmHg
• Flash Point: 192.7°C
• PSA: 75.35000
• Density: g/cm³
• LogP: 3.95570
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 242.199428076
• Heavy Atom Count: 17
• Complexity: 159

Purity/Quality:

98%,99%, ^*data from raw suppliers

CHC ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)[NH3+].C1CCC(CC1)NC(=O)[O-]

Technology Process of cyclohexylazanium;N-cyclohexylcarbamate

There total 1 articles about cyclohexylazanium;N-cyclohexylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

carbon dioxide (124-38-9,18923-20-1) + cyclohexylamine (108-91-8,157973-60-9) → cyclohexylammonium N-cyclohexylcarbamate (20190-03-8)

Guidance literature:

In tetrahydrofuran; at 19.9 ℃; under 772.6 Torr;

DOI:10.1016/S0040-4020(01)92239-2

Reference yield: 98.0%

cyclohexylammonium N-cyclohexylcarbamate (20190-03-8) + cyclohexylamine (108-91-8,157973-60-9) → Cyclohexyl isocyanate (3173-53-3)

Guidance literature:

With tetrachlorosilane; In tetrahydrofuran;

Reference yield: 93.0%

para-iodoanisole (696-62-8) + cyclohexylammonium N-cyclohexylcarbamate (20190-03-8) → N-cyclohexyl-4-methoxybenzamide (33739-91-2)

Guidance literature:

With triethylamine; triphenylphosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1,4-dioxane; at 80 ℃; for 24h; Schlenk technique;

DOI:10.1002/cssc.201800902

upstream raw materials:

carbon dioxide

cyclohexylamine

Downstream raw materials:

N-(trimethylsilyl)carbamatocyclohexane

carbon dioxide

cyclohexylamine

benzyl N-cyclohexylcarbamate

Refernces

• 1、 Cheng, Bin-Bin,Yu, Bing,Hu, Chang-Wen. "Indirect conversion of ambient pressure CO2 into oxazolidin-2-ones by a copper-based magnetic nanocatalyst". . p. 87179 - 87187. Retrieved 2016.
• 2、 Chen, Xiao-Chao,Yao, Yin-Qing,Zhao, Kai-Chun,Liu, Lei,Lu, Yong,Liu, Ye. "Cooperative Catalysis of Ru(III)-Porphyrin in CO2-Involved Synthesis of Oxazolidinones". . p. 2504 - 2510. Retrieved 2021/07/28.