PHENETHYLMETHYLDICHLOROSILANE

Base Information

• Chemical Name: PHENETHYLMETHYLDICHLOROSILANE
• CAS No.: 772-65-6
• Molecular Formula: C9H12Cl2Si
• Molecular Weight: 219.186
• European Community (EC) Number: 212-253-6
• UNII: 7XT4QT22F3
• DSSTox Substance ID: DTXSID1044988
• Nikkaji Number: J24.933E
• Wikidata: Q27268989
• Mol file: 772-65-6.mol

Synonyms:Silane,dichloromethyl(2-phenylethyl)- (9CI);Silane, dichloromethylphenethyl-(6CI,7CI,8CI);Dichloromethyl(2-phenylethyl)silane;Dichloromethylphenethylsilane;Methyl(2-phenethyl)dichlorosilane;Phenethylmethyldichlorosilane;[2-[Dichloro(methyl)silyl]ethyl]benzene;

Chemical Property of PHENETHYLMETHYLDICHLOROSILANE

Chemical Property:

• Appearance/Colour: Colorless or yellowish transparent liquid
• Vapor Pressure: 0.0704mmHg at 25°C
• Refractive Index: n20/D 1.5130(lit.)
• Boiling Point: 237 °C at 760 mmHg
• Flash Point: 92.5 °C
• PSA: 0.00000
• Density: 1.111 g/cm³
• LogP: 3.77870
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 218.0085323
• Heavy Atom Count: 12
• Complexity: 131

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dichloro(methyl)(2-phenylethyl)silane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](CCC1=CC=CC=C1)(Cl)Cl

Technology Process of PHENETHYLMETHYLDICHLOROSILANE

There total 7 articles about PHENETHYLMETHYLDICHLOROSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.8%

Dichloromethylsilane (75-54-7) + styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) → (2-phenylethyl)methyldichlorosilane (772-65-6)

Guidance literature:

styrene; With Pt loaded on nitrolotriacetic acid-functionalized silica gel; at 60 ℃; for 0.5h;

Dichloromethylsilane; at 60 ℃; for 4h; Reagent/catalyst;

DOI:10.1039/c8ra01828f

Reference yield: 91.0%

2-chloroethylmethyldichlorosilane (7787-85-1) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → (2-phenylethyl)methyldichlorosilane (772-65-6)

Guidance literature:

With aluminium trichloride; at 20 ℃; for 1h;

DOI:10.1016/S0022-328X(00)00319-3

Reference yield: 89.0%

3-chloropropyltrichlorosilane (2550-06-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → (2-phenylethyl)methyldichlorosilane (772-65-6) + 1-phenyl-3-(trichlorosilyl)propane (13617-40-8)

Guidance literature:

With aluminium trichloride; at 20 ℃; for 1h;

DOI:10.1016/S0022-328X(00)00319-3

upstream raw materials:

Dichloromethylsilane

styrene

Dichloromethylvinylsilane

benzene

Downstream raw materials:

dimethyl(2-phenylethyl)chlorosilane

1-<<2-(dichloromethylsilyl)ethyl>phenyl>adamantane

1,3-bis<<2-(dichloromethylsilyl)ethyl>phenyl>adamantane

Octamethyl-2.3-diphenethyl-tetrasiloxan

Refernces

• 1、 -. "PROCESS FOR THE STEPWISE SYNTHESIS OF SILAHYDROCARBONS". Page/Page column 71; 72. . Retrieved 2021/12/08.
• 2、 Shao, Dongyun,Li, Youxin. "Preparation of polycarboxylic acid-functionalized silica supported Pt catalysts and their applications in alkene hydrosilylation". . p. 20379 - 20393. Retrieved 2018/06/11.