exo-2-Chloronorbornane

Base Information

• Chemical Name: exo-2-Chloronorbornane
• CAS No.: 765-91-3
• Molecular Formula: C₇H₁₁Cl
• Molecular Weight: 130.617
• European Community (EC) Number: 624-578-4
• Mol file: 765-91-3.mol

Synonyms:exo-2-Chloronorbornane;765-91-3;(1S,4R)-2-CHLOROBICYCLO[2.2.1]HEPTANE;Exo-2-chloronorbornane,98%;exo-2-Chloronorbornane, 98%

Chemical Property of exo-2-Chloronorbornane

Chemical Property:

• Vapor Pressure: 3.29mmHg at 25°C
• Melting Point: -5 °C
• Refractive Index: n20/D 1.4854(lit.)
• Boiling Point: 66-66.5 °C30 mm Hg(lit.)
• Flash Point: 112 °F
• PSA: 0.00000
• Density: 1.06 g/mL at 25 °C(lit.)
• LogP: 2.41380
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 130.0549280
• Heavy Atom Count: 8
• Complexity: 101

Purity/Quality:

95% ^*data from raw suppliers

exo-2-Chloronorbornane 98% ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CC2CC1CC2Cl
• Isomeric SMILES: C1C[C@H]2C[C@@H]1CC2Cl
• Uses: exo-2-Chloronorbornane has been employed as reagent during Friedel-Crafts alkylation of benzene and substituted benzenes with tin(IV) chloride or aluminium trichloride.

Technology Process of exo-2-Chloronorbornane

There total 4 articles about exo-2-Chloronorbornane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

norbornene (279-23-2) → Norbornan-2-on (497-38-1) + 7-norbornanol (2566-48-5) + exo-2-norbornanol (497-37-0) + (+/-)-endo-2-norborneol (497-36-9) + exo-2-norbornyl chloride (67844-27-3) + endo-2-norbornyl chloride (765-91-3,2999-06-6,29342-53-8,36025-11-3,67844-26-2,67844-27-3,130726-60-2)

Guidance literature:

With tetrachloromethane; ozone; at 25 ℃; Rate constant; Product distribution; Mechanism; other norbornane derivatives, var. temperatures; E_a, log A per H;

DOI:10.1021/jo00250a005

Reference yield:

exo-2-norbornyloxychlorocarbene → norborn-2-ene (498-66-8) + nortricyclane (279-19-6) + exo-2-norbornyl chloride (67844-27-3) + endo-2-norbornyl chloride (765-91-3,2999-06-6,29342-53-8,36025-11-3,67844-26-2,67844-27-3,130726-60-2)

Guidance literature:

In 1,2-dichloro-ethane; at 25 ℃; Further Variations:; Reagents; Solvents; Kinetics; Product distribution;

DOI:10.1021/ja010598q

Reference yield:

endo-2-norbornyloxychlorocarbene → norborn-2-ene (498-66-8) + nortricyclane (279-19-6) + exo-2-norbornyl chloride (67844-27-3) + endo-2-norbornyl chloride (765-91-3,2999-06-6,29342-53-8,36025-11-3,67844-26-2,67844-27-3,130726-60-2)

Guidance literature:

In 1,2-dichloro-ethane; at 25 ℃; Further Variations:; Reagents; Solvents; Kinetics;

DOI:10.1021/ja010598q

upstream raw materials:

Norbornan-2-on

norbornene

Downstream raw materials:

2endo-Methoxycarbonyl-norbornan

exo-2-(methoxycarbonyl)norbornane

norbornene

exo-2-bromonorbornane

Refernces

• 1、 Kopp, Paul J.,Adkins, Rick L.. "Photochemistry of alkyl halides. 12. Bromides vs Iodides". . p. 2709 - 2717. Retrieved 2007/10/02.