Octanal 2,4-dinitrophenylhydrazone

Base Information

• Chemical Name: Octanal 2,4-dinitrophenylhydrazone
• CAS No.: 1726-77-8
• Molecular Formula: C14H20 N4 O4
• Molecular Weight: 308.337
• Hs Code.: 2928000090
• NSC Number: 402247
• Mol file: 1726-77-8.mol

Synonyms:1726-77-8;Octanal 2,4-dinitrophenylhydrazone;2,4-dinitro-N-[(E)-octylideneamino]aniline;2,4-dinitro-N-(octylideneamino)aniline;Octyl aldehyde-2,4-DNPH;NSC402247;AKOS024319320;NSC-402247;J-010839;Octanal 2,4-dinitrophenylhydrazone, analytical standard

Chemical Property of Octanal 2,4-dinitrophenylhydrazone

Chemical Property:

• Vapor Pressure: 3.58E-08mmHg at 25°C
• Melting Point: 98-101 °C
• Boiling Point: 446.7°Cat760mmHg
• Flash Point: 223.9°C
• PSA: 116.03000
• Density: 1.23g/cm³
• LogP: 5.38060
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 8
• Exact Mass: 308.14845513
• Heavy Atom Count: 22
• Complexity: 378

Purity/Quality:

99% ^*data from raw suppliers

Octanal 2,4-dinitrophenylhydrazone analytical standard ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCC=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-]
• Isomeric SMILES: CCCCCCC/C=N/NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Octanal 2,4-dinitrophenylhydrazone

There total 11 articles about Octanal 2,4-dinitrophenylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

octanal oxime (929-55-5) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → octanal (2,4-dinitrophenyl)hydrazone (1726-77-8)

Guidance literature:

iron(III) perchlorate; In 1,2-dichloro-ethane; at 20 ℃; for 4h;

DOI:10.1016/j.mencom.2007.05.021

Reference yield:

trioleoylglycerol (122-32-7) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → 2-undecenal (53448-07-0,71277-05-9,2463-77-6) + heptanal 2,4-dinitrophenylhydrazone (2074-05-7) + Δ2-Decenal-(2,4-dinitro-phenylhydrazon) (4237-03-0) + decanal (2,4-dinitrophenyl)hydrazone (1527-95-3) + 1-(hexylidene)-2-(2,4-dinitrophenyl)hydrazine (1527-97-5) + octanal (2,4-dinitrophenyl)hydrazone (1726-77-8) + nonanal (2,4-dinitrophenyl)hydrazone (2348-19-8,74335-75-4,74335-76-5)

Guidance literature:

trioleoylglycerol; With air; at 120 ℃; for 10h;

(2,4-dinitro-phenyl)-hydrazine; In acetonitrile; for 1h; Darkness;

DOI:10.1007/s00706-017-2036-3

Reference yield:

Octanal (124-13-0) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → octanal (2,4-dinitrophenyl)hydrazone (1726-77-8)

Guidance literature:

upstream raw materials:

Octanal

(2,4-dinitro-phenyl)-hydrazine

2-heptyl-1,3-dioxolane

heptyl-[1,3,5]trioxane

Refernces

• 1、 Yusubov, Mekhman S.,Svitich, Dmitrii Yu.,Yoshimura, Akira,Nemykin, Victor N.,Zhdankin, Viktor V.. "2-Iodoxybenzoic acid organosulfonates: Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants". supporting information. p. 11269 - 11271. Retrieved 2013/12/04.
• 2、 Mathew, Sindhu,Grey, Carl,Rumpunen, Kimmo,Adlercreutz, Patrick. "Analysis of carbonyl compounds in sea buckthorn for the evaluation of triglyceride oxidation, by enzymatic hydrolysis and derivatisation methodology". experimental part. p. 1399 - 1405. Retrieved 2012/02/03.