DECYL ALDEHYDE (DNPH DERIVATIVE)

Base Information

• Chemical Name: DECYL ALDEHYDE (DNPH DERIVATIVE)
• CAS No.: 1527-95-3
• Molecular Formula: C16H24 N4 O4
• Molecular Weight: 336.391
• Hs Code.: 2928000090
• Mol file: 1527-95-3.mol

Synonyms:Decanal,(2,4-dinitrophenyl)hydrazone (6CI,7CI,8CI,9CI)

Chemical Property of DECYL ALDEHYDE (DNPH DERIVATIVE)

Chemical Property:

• Melting Point: 100-104 °C
• PSA: 116.03000
• LogP: 6.16080

Purity/Quality:

99% ^*data from raw suppliers

Decanal 2,4-dinitrophenylhydrazone analytical standard ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DECYL ALDEHYDE (DNPH DERIVATIVE)

There total 8 articles about DECYL ALDEHYDE (DNPH DERIVATIVE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

n-decanal oxime (13372-74-2) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → decanal (2,4-dinitrophenyl)hydrazone (1527-95-3)

Guidance literature:

iron(III) perchlorate; In 1,2-dichloro-ethane; at 20 ℃; for 6h;

DOI:10.1016/j.mencom.2007.05.021

Reference yield:

trioleoylglycerol (122-32-7) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → 2-undecenal (53448-07-0,71277-05-9,2463-77-6) + heptanal 2,4-dinitrophenylhydrazone (2074-05-7) + Δ2-Decenal-(2,4-dinitro-phenylhydrazon) (4237-03-0) + decanal (2,4-dinitrophenyl)hydrazone (1527-95-3) + 1-(hexylidene)-2-(2,4-dinitrophenyl)hydrazine (1527-97-5) + octanal (2,4-dinitrophenyl)hydrazone (1726-77-8) + nonanal (2,4-dinitrophenyl)hydrazone (2348-19-8,74335-75-4,74335-76-5)

Guidance literature:

trioleoylglycerol; With air; at 120 ℃; for 10h;

(2,4-dinitro-phenyl)-hydrazine; In acetonitrile; for 1h; Darkness;

DOI:10.1007/s00706-017-2036-3

Reference yield:

caprinaldehyde (112-31-2) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → decanal (2,4-dinitrophenyl)hydrazone (1527-95-3)

Guidance literature:

upstream raw materials:

caprinaldehyde

(2,4-dinitro-phenyl)-hydrazine

1-ethoxydec-1-ene

n-decanal oxime

Refernces

• 1、 Guo, Yuan,Lu, Zhenhuan,Yao, Libo,Shi, Zhen. "A novel synthetic method for the preparation of aliphatic aldehydes from the corresponding carboxylic acids". experimental part. p. 489 - 492. Retrieved 2012/01/05.
• 2、 Oskooie, Hossien A.,Heravi, Majid M.,Sadnia, Akbar,Safarzadegan, Mehrak,Behbahani, Farahnaz K.. "Mild and efficient conversion of oximes into arylhydrazones catalysed by ferric perchlorate". . p. 190 - 191. Retrieved 2008/02/03.