CID 11789437

Base Information

• Chemical Name: CID 11789437
• CAS No.: 6945-92-2
• Molecular Formula: C4H10N2O2^.HCl
• Molecular Weight: 154.597
• Hs Code.: 29280000
• Mol file: 6945-92-2.mol

Synonyms:

Chemical Property of CID 11789437

Chemical Property:

• Appearance/Colour: White crystal
• Vapor Pressure: 0.0988mmHg at 25°C
• Melting Point: 152-154 °C(lit.)
• Boiling Point: 223 °C at 760 mmHg
• Flash Point: 88.6 °C
• PSA: 64.35000
• LogP: 0.90600
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 154.0509053
• Heavy Atom Count: 9
• Complexity: 74.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ethyl hydrazinoacetate hydrochloride ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCOC(=O)CN[NH3+].[Cl-]
• Uses: Ethyl hydrazinoacetate hydrochloride has been used in the preparation of three novel copper(II) complexes as condensation derivatives of 2-pyridinecarboxaldehyde, 2-acetylpyridine and 2-quinolinecarboxaldehyde.

Technology Process of CID 11789437

There total 3 articles about CID 11789437 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.4%

(N'-tert-butoxycarbonyl-hydrazino)acetic acid ethyl ester (3842-39-5) → 2-hydrazinyl acetic acid ethyl ester hydrochloride (6945-92-2)

Guidance literature:

With hydrogenchloride; In ethanol; water; Reflux;

Reference yield: 84.0%

ethyl glyoxylate hydrazone → 2-hydrazinyl acetic acid ethyl ester hydrochloride (6945-92-2)

Guidance literature:

ethyl glyoxylate hydrazone; With palladium 10% on activated carbon; hydrogen; at 30 ℃; for 20h; Large scale;

With hydrogenchloride; In water; at 5 ℃; for 2h; pH=1; Large scale;

Reference yield:

hydrazineacetic acid (14150-64-2) → 2-hydrazinyl acetic acid ethyl ester hydrochloride (6945-92-2)

Guidance literature:

With hydrogenchloride; ethanol;

upstream raw materials:

hydrazineacetic acid

(N'-tert-butoxycarbonyl-hydrazino)acetic acid ethyl ester

Downstream raw materials:

3-(5-nitrofurfurylideneamino)hydantoic acid

[3-Methyl-5-(2-nitro-phenyl)-pyrazol-1-yl]-acetic acid

[3-Methyl-5-(2-nitro-phenyl)-pyrazol-1-yl]-acetic acid ethyl ester

[4-(4-methoxyphenyl)-1(2H)-oxophthalazin-2-yl]acetic acid ethyl ester

Refernces

• 1、 -. "Preparation method of ethyl hydrazinoacetate hydrochloride". Paragraph 0014; 0016; 0018; 0020; 0022; 0024. . Retrieved 2019/01/16.