Triethyliodotin(IV)

Base Information

• Chemical Name: Triethyliodotin(IV)
• CAS No.: 2943-86-4
• Molecular Formula: C6H15 I Sn
• Molecular Weight: 332.8
• NSC Number: 202915
• UNII: WPS453B617
• DSSTox Substance ID: DTXSID40308279
• Wikidata: Q27292773
• Mol file: 2943-86-4.mol

Synonyms:Tin,triethyliodo- (7CI); Triethyltin iodide (6CI); Iodotriethylstannane; NSC202915; NSC 203240; Triethyliodostannane; Triethylstannyl iodide

Chemical Property of Triethyliodotin(IV)

Chemical Property:

• Vapor Pressure: 0.287mmHg at 25°C
• Boiling Point: 209.8°Cat760mmHg
• Flash Point: 80.7°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.42660
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 333.92405
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Sn](CC)(CC)I

Technology Process of Triethyliodotin(IV)

There total 21 articles about Triethyliodotin(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hexaethyl distannane (993-63-5) → triethyltin iodide (2943-86-4) + triethyl(phenyl)stannane (878-51-3)

Guidance literature:

With iodobenzene; dichloro bis(acetonitrile) palladium(II); In N,N,N,N,N,N-hexamethylphosphoric triamide; 20°C, molar ratio distannane/halide 2.0:1, 120 min;

DOI:10.1007/BF01141722

Reference yield: 88.0%

1-(2-(triethylstannylthio)ethyl)silatrane + methyl iodide (74-88-4) → triethyltin iodide (2943-86-4) + 1-(β-Methylthioethyl)silatrane (96919-97-0)

Guidance literature:

In diethyl ether; for 7.5h; Darkness;

DOI:10.1134/S107036320811011X

Reference yield: 81.0%

p-nitrobenzene iodide (636-98-6) + hexaethyl distannane (993-63-5) → triethyltin iodide (2943-86-4) + p-nitrophenyltriethylstannane (91734-78-0)

Guidance literature:

dichloro bis(acetonitrile) palladium(II); In N,N-dimethyl-formamide; 20°C, molar ratio distannane/halide 1.2:1, 5 min;

DOI:10.1007/BF01141722

upstream raw materials:

p-nitrobenzene iodide

carbon monoxide

triethylmethoxystannane

(Et)3tin(phenylthiolate)

Downstream raw materials:

triethyl(phenyl)stannane

(C₂H₅)3SnC₆H₄-p-Si(C₂H₅)3

(C₂H₅)3SnC₆H₄-p-CFCFCl

(C₂H₅)3SnC₆H₄-m-CF₃

Refernces

• 1、 Voronkov,Tsyrendorzhieva,Lis,Grinberg,Shatokhina,Rakhlin. "Acyl iodides in organic synthesis. Reactions with substituted bis(trimethylsilyl)amines". . p. 147 - 150. Retrieved 2013/03/28.
• 2、 Arbuzov, P. V.,Voronkov, M. G.,Mirskov, R. G.,Stankevich, V. K.,Kukharev, B. F.,et al.. "Homolytic addition of polyhaloalkanes to α-vinyloxy-ω-trialkylstannoxyalkanes as a new route to 2-perhaloalkylmethyl-substituted 1,3-dioxacyclanes". . p. 1755 - 1757. Retrieved 2007/10/03.