Triethyl(phenyl)stannane

Base Information

• Chemical Name: Triethyl(phenyl)stannane
• CAS No.: 878-51-3
• Molecular Formula: C12H20 Sn
• Molecular Weight: 283.001
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID80497994
• Mol file: 878-51-3.mol

Synonyms:triethyl(phenyl)stannane;878-51-3;MONOPHENYLTRIETHYLTIN;triethylphenyl stannane;Stannane, triethyl-, phenyl-;DTXSID80497994;CKGABOFCIIXWCH-UHFFFAOYSA-N

Chemical Property of Triethyl(phenyl)stannane

Chemical Property:

• PSA: 0.00000
• LogP: 3.40210
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 284.058703
• Heavy Atom Count: 13
• Complexity: 124

Purity/Quality:

99% ^*data from raw suppliers

MONOPHENYLTRIETHYLTIN 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Sn](CC)(CC)C1=CC=CC=C1

Technology Process of Triethyl(phenyl)stannane

There total 22 articles about Triethyl(phenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hexaethyl distannane (993-63-5) → triethyltin iodide (2943-86-4) + triethyl(phenyl)stannane (878-51-3)

Guidance literature:

With iodobenzene; dichloro bis(acetonitrile) palladium(II); In N,N,N,N,N,N-hexamethylphosphoric triamide; 20°C, molar ratio distannane/halide 2.0:1, 120 min;

DOI:10.1007/BF01141722

Reference yield: 82.0%

trimethyl(phenyl)stannane (934-56-5) + lithium triethylstannate (30295-76-2) → triethyl(phenyl)stannane (878-51-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In tetrahydrofuran; LiSnEt3 added to PhSnMe3 in THF, stirred at 50°C for 30 min, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products determined by GLC;

DOI:10.1246/bcsj.60.3299

Reference yield: 77.0%

chlorotriethylstannane (994-31-0) + phenyllithium (591-51-5) → triethyl(phenyl)stannane (878-51-3)

Guidance literature:

In diethyl ether; refluxing;;

DOI:10.1039/JR9600001566

upstream raw materials:

bromobenzene

trimethylstannyl iodide

hexaethyl distannane

diphenylmercury(II)

Downstream raw materials:

(C₂H₅)3SnC₆H₄-p-CH(OH)CH₃

(C₂H₅)3SnC₆H₄-p-COOH

(C₂H₅)3SnC₆H₄-m-I

(C₂H₅)3SnC₆H₄-m-Br

Refernces

• 1、 Mochida, Kunio. "Reactions of Trialkylstannane Anions R3Sn- with Arylstannanes ArSnR'3". . p. 3299 - 3306. Retrieved 2007/10/02.