2-hydroxyphenazine

Base Information

• Chemical Name: 2-hydroxyphenazine
• CAS No.: 4190-95-8
• Molecular Formula: C12H8N2O
• Molecular Weight: 196.2
• Hs Code.: 2933990090
• Mol file: 4190-95-8.mol

Synonyms:2-phenazinol;2-Hydroxy-5,10-diazaanthracene;2-Hydroxyphenazin;2-Hydroxy-phenazine;phenazin-2(10h)-one;phenazine-2-ol;phenazin-2-ol;

Chemical Property of 2-hydroxyphenazine

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 430.012°C at 760 mmHg
• Flash Point: 213.864°C
• PSA: 46.01000
• Density: 1.376g/cm³
• LogP: 2.48860

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-hydroxyphenazine

There total 26 articles about 2-hydroxyphenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

5,10-dioxy-phenazin-2-ol (303-80-0) → 2-hydroxyphenazine (4190-95-8)

Guidance literature:

With sodium hypophosphite; palladium on activated charcoal; In tetrahydrofuran; water; for 2h; Ambient temperature;

Reference yield: 73.0%

C12H10N2O3 → 2-hydroxyphenazine (4190-95-8)

Guidance literature:

With sulfur; sodium hydroxide; In methanol; water; at 80 ℃; for 16h; Green chemistry;

DOI:10.1002/ejoc.202000064

Reference yield: 72.0%

2-methoxyphenazine (2876-18-8) → 2-hydroxyphenazine (4190-95-8)

Guidance literature:

With boron tribromide; In dichloromethane; for 16h; Heating;

DOI:10.1021/ol050198y

upstream raw materials:

2-methoxyphenazine

phenazin-2-amine

2-chlorophenazine

2-ethoxyphenazine

Downstream raw materials:

5,10-dioxy-phenazin-2-ol

2-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)phenazine

2-Acetoxyphenazin

2-methoxyphenazine

Refernces

• 1、 Cerecetto, Hugo,Romero, Angel H.. "A Common, Facile and Eco-Friendly Method for the Reduction of Nitroarenes, Selective Reduction of Poly-Nitroarenes and Deoxygenation of N-Oxide Containing Heteroarenes Using Elemental Sulfur". supporting information. . Retrieved 2020/03/23.
• 2、 Kour, Harpreet,Paul, Satya,Singh, Parvinder Pal,Gupta, Rajive. "A mild and simple method for the synthesis of substituted phenazines". . p. 495 - 500. Retrieved 2014/03/21.