10-Ketomyristic acid

Base Information

• Chemical Name: 10-Ketomyristic acid
• CAS No.: 675-95-6
• Molecular Formula: C14H26O3
• Molecular Weight: 242.35
• Mol file: 675-95-6.mol

Synonyms:

Chemical Property of 10-Ketomyristic acid

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-Ketomyristic acid

There total 21 articles about 10-Ketomyristic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,10-tetradecanediol (188130-40-7) → 10-oxotetradecanoic acid (675-95-6)

Guidance literature:

With Jones reagent; In acetone; at 0 - 20 ℃; for 0.5h;

DOI:10.1021/jo500791y

Reference yield: 22.0%

10-Oxo-tetradecanal (142055-95-6) → 10-oxotetradecanoic acid (675-95-6)

Guidance literature:

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In water; tert-butyl alcohol; at 20 ℃; for 2h; Schlenk technique;

DOI:10.1002/anie.202114482

Reference yield:

n-tetradecanoic acid (544-63-8) + trifluoroacetic acid (76-05-1) → 13-oxotetradecanoic acid (2389-02-8) + 9-oxo-tetradecanoic acid (71173-32-5) + 10-oxotetradecanoic acid (675-95-6) + 8-Oxotetradecanoic acid (39747-88-1)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In dichloromethane; Yield given. Further byproducts given. Yields of byproduct given;

upstream raw materials:

n-butyl magnesium bromide

9-ethoxycarbonylnonanoic acid chloride

10-hydroxytetradecanoic acid

3,12-dihydroxy-hexadecanoic acid

Downstream raw materials:

10-hydroxytetradecanoic acid

Refernces

• 1、 Bergamaschi, Enrico,Chen, Yi-Kai,Hohenadel, Melissa,Lunic, Danijela,McLean, Liam A.,Teskey, Christopher J.. "Controlling Chemoselectivity of Catalytic Hydroboration with Light". . . Retrieved 2022/01/13.
• 2、 Hembrock, Annegret,Schaefer, Hans J.,Zimmermann, Gesine. "Selektivitaet der anodischen Oxidation von CH- und CH2-Gruppen; selektive Oxidation von Steroiden an C-6". . p. 1048 - 1049. Retrieved 2007/10/02.