Technology Process of GALLIUM TRIPHENYL
There total 10 articles about GALLIUM TRIPHENYL which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
neat (no solvent);
Ga was mixed with HgPh2 in air, several cycles of pumping and refilling with N2, stirred at 170°C for 5 h, solidified at ambient temp.; ppt. was dissolved in toluene, stored at -20°C, concd., stored at-20°C;
DOI:10.1021/ic010877e
- Guidance literature:
-
In
benzene;
react. under vac.; combination of Ph2GaCl and As-compd. in C6H6 (ratio Ph2GaCl : As-compd. = 3:1) in a bulb (cooled to -196°C, degassed), stirring for 16 days at 80°C; removal of solvent and Me3SiCl in vac., extn. with hot ligroin, addn. of C7H8 to the hot ext., cooling to -17°C for 3 days;
DOI:10.1016/0022-328X(90)85445-5
- Guidance literature:
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In
neat (no solvent);
(C6H5)Ga(CH3)2 was evacuated into a Schlenk flask, heated to 150°C for 30 min; not sepd., detected by NMR spectra;
DOI:10.1021/om701055a
