Benzimidic acid ethyl

Base Information

• Chemical Name: Benzimidic acid ethyl
• CAS No.: 825-60-5
• Molecular Formula: C9H11NO
• Molecular Weight: 149.192
• Mol file: 825-60-5.mol

Synonyms:benzenecarboximidic acid ethyl ester;Diacetylspermine;benzimidic acid ethyl ester;Benziminoaethylaether;phenylimidate d'ethyle;N',N''-Diacetylspermine;Benzimidsaeure-aethylester;ethyl benzimidate;benzimide acid ethylester;

Chemical Property of Benzimidic acid ethyl

Chemical Property:

• Boiling Point: 192.9°Cat760mmHg
• PKA: 6.28±0.43(Predicted)
• Flash Point: 70.5°C
• PSA: 33.08000
• Density: 0.98g/cm³
• LogP: 2.14820

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzimidic acid ethyl

There total 18 articles about Benzimidic acid ethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

benzonitrile (100-47-0) + acetyl chloride (75-36-5) → benzimidic acid ethyl ester (825-60-5)

Guidance literature:

In ethanol; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1039/d0cc02728f

Reference yield: 94.2%

ethanol (64-17-5) + benzonitrile (100-47-0) → benzimidic acid ethyl ester (825-60-5)

Guidance literature:

With acetyl chloride; at 25 ℃; for 16h;

DOI:10.1002/ejoc.200400591

Reference yield: 89.0%

ethyl benzimidate hydrochloride (5333-86-8) → benzimidic acid ethyl ester (825-60-5)

Guidance literature:

With potassium hydroxide; water;

upstream raw materials:

N-ethylchloro(phenyl)methanimine

sodium ethanolate

benzamide

ethyl iodide

Downstream raw materials:

N¹-isonicotinoylbenzamidrazone

N-propionyl-benzimidic acid ethyl ester

2-phenyl-4-cyclohexylidene-2-imidazoline-5-one

6-methyl-2-phenyl-3H-pyrimidin-4-one

Refernces

• 1、 Li, Guangfu,Yang, Tianzhi,Shao, Kuizhan,Gao, Ying,Shan, Guogang,Su, Zhongmin,Wang, Xinlong,Zhu, Dongxia. "Understanding Mechanochromic Luminescence on Account of Molecular Level Based on Phosphorescent Iridium(III) Complex Isomers". . p. 3741 - 3748. Retrieved 2021/04/07.
• 2、 -. "Synthesis method of cyanoacrylate compound". Paragraph 0020; 0024; 0025; 0030; 0031. . Retrieved 2021/09/21.