Dichloro(1,2-diaminoethane)palladium

Base Information

• Chemical Name: Dichloro(1,2-diaminoethane)palladium
• CAS No.: 15020-99-2
• Molecular Formula: C2H8 Cl2 N2 Pd
• Molecular Weight: 237.425
• Hs Code.: 28439000
• European Community (EC) Number: 625-199-7
• Mol file: 15020-99-2.mol

Synonyms:15020-99-2;Dichloro(1,2-diaminoethane)palladium;Dichloro(ethylenediamine)palladium(II);(Ethylenediamine)palladium(II) chloride;dichloropalladium;ethane-1,2-diamine;Dichloro(ethylenediamine)palladate(II);Dichloro(ethylenediamine)palladium(II), Pd 44.8%;SCHEMBL310650;MFCD00044991;AKOS015901901;FT-0637174;(Ethylenediamine)palladium(II) chloride, 97%;?DICHLORO(ETHYLENEDIAMINE)PALLADIUM(II);F87443;A884187;(Ethylenediamine)palladium(II) chloride, >=99.99%

Chemical Property of Dichloro(1,2-diaminoethane)palladium

Chemical Property:

• Vapor Pressure: 15.8mmHg at 25°C
• Melting Point: >278 °C(lit.)
• Boiling Point: 119.7°Cat760mmHg
• Flash Point: 33.9°C
• PSA: 24.06000
• Density: g/cm³
• LogP: 1.13080
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Hygroscopic
• Water Solubility.: Very low solubility in water.
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 235.90993
• Heavy Atom Count: 7
• Complexity: 8.8

Purity/Quality:

99% ^*data from raw suppliers

(Ethylenediamine)palladium(II) chloride 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(CN)N.Cl[Pd]Cl
• Uses: Catalyst for C-C coupling reactions like Sonogashira coupling. Formation of host-guest complexes. Synthesis of mixed-metal, mixed-pyrimidine self-assembling metallacalix[n]arenes; ring-in-ring complex; binding of metal with glycose phosphates. Catalyst for: Synthesis of 6-(substituted benzyl)imidazo[2,1-b][1,3]thiazoleSonogashira-coupling reactionsReactant for:Self-assembly of a ring-in-ring complexMetal binding with glycose phosphatesSynthesis of mixed-mtal, mixed-pyrimidine self-assembling metallacalix[n]arenes

Technology Process of Dichloro(1,2-diaminoethane)palladium

There total 24 articles about Dichloro(1,2-diaminoethane)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ethylen diammonium tetrachloropalladate (II) → Pd(ethylenediamine)Cl2 (15020-99-2)

Guidance literature:

In neat (no solvent); byproducts: HCl; isothermal decompn. at 183°C; elem. anal.;

Reference yield: 97.0%

dichloro-(1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene)palladium (570397-18-1) + ethylenediamine (107-15-3,85404-18-8) → cis-dichloro(ethylenediamine)palladium(II) (15020-99-2)

Guidance literature:

In dimethyl sulfoxide; 100°C, 10 min; monitored by (1)H NMR;

DOI:10.1016/j.poly.2012.04.006

Reference yield: 84.0%

potassium tetrachloropalladate(II) (10025-98-6) + ethylenediamine (107-15-3,85404-18-8) → cis-dichloro(ethylenediamine)palladium(II) (15020-99-2)

Guidance literature:

at 35 - 40 ℃;

DOI:10.1080/15533174.2013.862652

upstream raw materials:

dichloro (ethylen diethyl sulfide) palladium (II)

ethylenediamine

bis-(ethylendiamine)palladium(II) tetrachloropalladate (II)

potassium tetrachloropalladate(II)

Downstream raw materials:

[Pd(H₂NCH₂CH₂NH₂)((C₆H₅)2P(O)NP(S)(C₆H₅)2)2]

[Pd(H₂NCH₂CH₂NH₂)((C₆H₅)2P(O)NP(Se)(C₆H₅)2)2]

tetramminepalladium(II) chloride

bis(ethylenediamine)palladium(II) chloride

Refernces

• 1、 Tercero-Moreno,Matilla-Hernandez,Gonzalez-Garcia,Niclos-Gutierrez. "Hydrolytic species of the ion cis-diaqua(ethylenediamine) palladium (II) complex and of cis-dichloro (ethylenediamine) palladium (II): Fitting its equilibrium models in aqueous media with or without chloride ion". . p. 23 - 29. Retrieved 1996.
• 2、 Khalaf Alla, Perihan A.,Shoukry, Mohamed M.,Van Eldik, Rudi. "Amine-bridged binuclear complexes involving [Pd(ethylenediamine)(H2O)2]2+, 4,4'-bipiperidine and DNA constituents". . p. 2041 - 2053. Retrieved 2015.
• 3、 Agnes, Marco,Nitti, Andrea,Vander Griend, Douglas A.,Dondi, Daniele,Merli, Daniele,Pasini, Dario. "A chiroptical molecular sensor for ferrocene". supporting information. p. 11492 - 11495. Retrieved 2016/10/03.