N-methyl-4-nitro-1-naphthalenamine

Base Information

• Chemical Name: N-methyl-4-nitro-1-naphthalenamine
• CAS No.: 7000-88-6
• Molecular Formula: C11H10N2O2
• Molecular Weight: 202.20900
• Mol file: 7000-88-6.mol

Synonyms:1-(methylamino)-4-nitronaphthalene;N-Methyl-4-nitro-[1]naphthylamin;Methyl-(4-nitro-[1]naphthyl)-amin;4-Nitro-1-methylamino-naphthalin;methyl-(4-nitro-[1]naphthyl)-amine;4-Nitro-N-methyl-[1]naphthylamin;

Chemical Property of N-methyl-4-nitro-1-naphthalenamine

Chemical Property:

• PSA: 57.85000
• LogP: 3.38590

Purity/Quality:

95% ^*data from raw suppliers

N-METHYL-4-NITRO-1-NAPHTHALENAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-methyl-4-nitro-1-naphthalenamine

There total 4 articles about N-methyl-4-nitro-1-naphthalenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

1-amino-4-nitronaphthalene (776-34-1) + dimethyl sulfate (77-78-1) → N-methyl-4-nitro-α-naphthylamine (7000-88-6) + 1-(dimethylamino)-4-nitronaphthalene (39139-76-9)

Guidance literature:

With sodium carbonate; In methanol; water; at 20 ℃; for 70h;

DOI:10.1002/ejoc.200390085

Reference yield:

1-fluoro-4-nitronaphthalene (341-92-4) + methylamine (74-89-5) → N-methyl-4-nitro-α-naphthylamine (7000-88-6)

Guidance literature:

In ethanol; Heating;

DOI:10.1021/jo00228a012

Reference yield:

1-chloro-4-nitronaphthalene (605-61-8) + methylamine (74-89-5) → N-methyl-4-nitro-α-naphthylamine (7000-88-6)

Guidance literature:

upstream raw materials:

1-amino-4-nitronaphthalene

dimethyl sulfate

1-chloro-4-nitronaphthalene

methylamine

Downstream raw materials:

N-methyl-N-(4-nitro-[1]naphthyl)-acetamide

Refernces

• 1、 Bunce, Nigel J.,Cater, Stephen R.,Scaiano, J. C.,Johnston, Linda J.. "Photosubstitution of 1-Methoxy-4-nitronaphthalene with Amine Nucleophiles: Dual Pathways". . p. 4214 - 4223. Retrieved 2007/10/02.