1,2,4,3,5-Trithiadiborolane

Base Information

• Chemical Name: 1,2,4,3,5-Trithiadiborolane
• CAS No.: 765-35-5
• Molecular Formula: B2H2S3
• Molecular Weight: 119.836
• Mol file: 765-35-5.mol

Synonyms:1,2,4,3,5-Trithiadiborolane;cyclo-1,2,4-Trithia-3,5-diboran;

Chemical Property of 1,2,4,3,5-Trithiadiborolane

Chemical Property:

• PSA: 82.69000
• LogP: 1.18300

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2,4,3,5-Trithiadiborolane

There total 4 articles about 1,2,4,3,5-Trithiadiborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,5-bis(dimethylamino)-1,2,4,3,5-trithiaborolane (77333-20-1) + diborane (19287-45-7) → cyclo-1,2,4-Trithia-3,5-diboran (765-35-5) + tris(dimethylamino)borane (4375-83-1)

Guidance literature:

In tetrahydrofuran; stoichiometric diborane, in NMR tube; not isolated, detected by NMR;

Reference yield:

3,5-bis(dimethylamino)-1,2,4,3,5-trithiaborolane (77333-20-1) + diborane (19287-45-7) → dimethylamine borane (1838-13-7) + cyclo-1,2,4-Trithia-3,5-diboran (765-35-5) + bis(dimethylamino)borane (2386-98-3)

Guidance literature:

In tetrahydrofuran; excess of diborane, in NMR tube; not isolated, detected by NMR;

Reference yield:

9-borabicyclo[3.3.1]nonane dimer (21205-91-4) + 3,5-dibromo-1,2,4-trithia-3,5-diborolane (13863-77-9) → B-Br-9-BBN (22086-45-9) + cyclo-1,2,4-Trithia-3,5-diboran (765-35-5)

Guidance literature:

In benzene-d6; in NMR tube, 15 min; not isolated, detected by NMR;

upstream raw materials:

9-borabicyclo[3.3.1]nonane dimer

3,5-dibromo-1,2,4-trithia-3,5-diborolane

3,5-bis(dimethylamino)-1,2,4,3,5-trithiaborolane

tetrapropyldiborane⁽⁶⁾

Downstream raw materials:

3,5-di-1-styryl-1,2,4,3,5-trithiadiborolane