2-Fluoropropane

Base Information

• Chemical Name: 2-Fluoropropane
• CAS No.: 420-26-8
• Molecular Formula: C3H7 F
• Molecular Weight: 62.087
• Hs Code.: 2903399090
• DSSTox Substance ID: DTXSID0073902
• Nikkaji Number: J5.724J
• Wikidata: Q209391,Q82948907
• Mol file: 420-26-8.mol

Synonyms:2-FLUOROPROPANE;Propane, 2-fluoro-;420-26-8;Isopropyl fluoride;R 281ea;iso-C3H7F;C3H7F;DTXSID0073902;MFCD00040106;AKOS006227769;FT-0612453;Q209391

Chemical Property of 2-Fluoropropane

Chemical Property:

• Vapor Pressure: 2580mmHg at 25°C
• Melting Point: -133,4°C
• Refractive Index: 1.3282
• Boiling Point: -10°C
• PSA: 0.00000
• Density: 0.969
• LogP: 1.36430
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 62.053178385
• Heavy Atom Count: 4
• Complexity: 10.8

Purity/Quality:

98%Min ^*data from raw suppliers

2-Fluoropropane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Statements: 12
• Safety Statements: 9-16-23-33

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)F

Technology Process of 2-Fluoropropane

There total 9 articles about 2-Fluoropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

isobutyric Acid (79-31-2) → propane (74-98-6) + 2-propylfluoride (420-26-8)

Guidance literature:

With AgF*HF; titanium(IV) oxide; In acetonitrile; Irradiation;

DOI:10.1021/jo00058a019

Reference yield:

AgCF(CF3)2*CH3CN → perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + 2-propylfluoride (420-26-8) + perfluoro(2,3-dimethylbutane) (354-96-1) + silver (7440-22-4) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

In neat (no solvent); decompn. at 100°C;; molar ratio ((CF3)2CF)2, (CF3)2CHF, C3F6=33:7:2;;

DOI:10.1021/ja01028a047

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → carbon tetrafluoride (75-73-0) + freon-218 (76-19-7) + propane (74-98-6) + 2-propylfluoride (420-26-8) + 2,2-difluoropropane (420-45-1) + Hexafluoroethane (76-16-4)

Guidance literature:

With hydrogen fluoride; sodium fluoride; at 0 ℃; for 18h; Product distribution; electrochemical fluorination; anode and cathode: nickel foam; anode potential versus nickel reference electrod 4.0 V; effect of anode potential; effect of dilution; effect of propene flow rate; effect of the anode conditioning;

DOI:10.1016/S0022-1139(00)80509-6

upstream raw materials:

(2,2-dichloro-1,1-difluoro-ethyl)-isopropyl ether

toluene-4-sulfonic acid isopropyl ester

propene

propane

Downstream raw materials:

2-methylisopropylbenzene

m-cymene

4-methylisopropylbenzene

propane

Refernces

• 1、 Zhao, Shu-Bin,Becker, Jennifer J.,Gagne, Michel R.. "Steric crowding makes challenging Csp3 - F reductive eliminations feasible". scheme or table. p. 3926 - 3929. Retrieved 2011/10/03.
• 2、 Arimura, Takashi,Shibakami, Motonari,Tamura, Masanori,Kurosawa, Shigeru,Sekiya, Akira. "Perfluorination of Allene Derivatives by Direct Fluorination". . p. 588 - 598. Retrieved 2007/10/02.