dichloroplatinum(2+) (1-phenylethane-1,2-diyl)diazanide

Base Information

• Chemical Name: dichloroplatinum(2+) (1-phenylethane-1,2-diyl)diazanide
• CAS No.: 72426-83-6
• Molecular Formula: C₈H₁₂Cl₂N₂Pt
• Molecular Weight: 402.183
• Mol file: 72426-83-6.mol

Synonyms:1, 2-Ethanediamine, 1-phenyl-, platinum dichloride complex;

Chemical Property of dichloroplatinum(2+) (1-phenylethane-1,2-diyl)diazanide

Chemical Property:

• Vapor Pressure: 0.0108mmHg at 25°C
• Boiling Point: 262.6°Cat760mmHg
• Flash Point: 132.3°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dichloroplatinum(2+) (1-phenylethane-1,2-diyl)diazanide

There total 2 articles about dichloroplatinum(2+) (1-phenylethane-1,2-diyl)diazanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

potassium tetrachloroplatinate(II) (10025-99-7) + (R/S)-1,2-diamino-1-phenylethane dihydrochloride (4921-62-4,16635-94-2,98300-61-9,98300-62-0,132316-54-2) → PtCl2((R/S)-1,2-diamino-1-phenylethane) (80339-76-0,72426-83-6)

Guidance literature:

In water; stoich. amts., stirring in dark at room temp. with pH-adjustment to 2.5-3.0 for 2 d and to 5.5-6.0 for further 3 d (pptn.); collection (filtration), washing (0.1 M HCl, water, drying (vac., 60°C, over P2O5);

DOI:10.1016/s0020-1693(97)05603-x

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + (-)-1,2-diamino-1-phenyl-ethane → PtCl2((R/S)-1,2-diamino-1-phenylethane) (80339-76-0,72426-83-6)

Guidance literature:

In diethyl ether; water; addn. of 1,2-diamino-1-phenylethane in ether to a soln. of K2(PtCl4) in H2O at 40°C under stirring for 4 h;;

Reference yield:

(-)-1,2-diamino-1-phenyl-ethane + PtCl2((R/S)-1,2-diamino-1-phenylethane) (80339-76-0,72426-83-6) → d-{Ptl-phn2}l2*H2O

Guidance literature:

In water; addn. of l-1,2-diamino-1-phenyl-ethane to a suspension of (Ptl-phnCl2) in H2O, addn. of H2O and heating for 2 h at 90°C; conc. at distillation of H2O in vac.; crystallisation in a desiccator;;

upstream raw materials:

potassium tetrachloroplatinate(II)

(R/S)-1,2-diamino-1-phenylethane dihydrochloride

Refernces