Furfuryl methacrylate

Base Information

• Chemical Name: Furfuryl methacrylate
• CAS No.: 3454-28-2
• Deprecated CAS: 1571152-10-7
• Molecular Formula: C9H10O3
• Molecular Weight: 166.177
• Hs Code.: 29321900
• European Community (EC) Number: 222-383-5
• NSC Number: 61377,24164
• DSSTox Substance ID: DTXSID9063037
• Nikkaji Number: J216.128A
• Wikidata: Q81990446
• Mol file: 3454-28-2.mol

Synonyms:furfuryl methacrylate

Chemical Property of Furfuryl methacrylate

Chemical Property:

• Vapor Pressure: 0.139mmHg at 25°C
• Refractive Index: n20/D 1.482(lit.)
• Boiling Point: 216.6 °C at 760 mmHg
• Flash Point: 84.8 °C
• PSA: 39.44000
• Density: 1.086 g/cm³
• LogP: 1.89890
• Storage Temp.: Amber Vial, Refrigerator
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 166.062994177
• Heavy Atom Count: 12
• Complexity: 186

Purity/Quality:

98%,99%, ^*data from raw suppliers

Furfuryl Methacrylate (stabilized with MEHQ) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC1=CC=CO1

Technology Process of Furfuryl methacrylate

There total 7 articles about Furfuryl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → furan-2-ylmethyl methacrylate (3454-28-2)

Guidance literature:

With N-phenyl-maleimide; 2-methylbenzene-1,4-diol; zinc diacetate; at 120 - 140 ℃; for 12h; Reagent/catalyst; Concentration; Temperature;

Reference yield:

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + methyl methacrylate (97-63-2,9003-42-3) → furan-2-ylmethyl methacrylate (3454-28-2)

Guidance literature:

With N-phenyl-maleimide; 2-methylbenzene-1,4-diol; 1,8-diazabicyclo[5.4.0]undec-7-ene; at 120 - 140 ℃; for 12h; Temperature;

Reference yield:

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + propyl methacrylate (2210-28-8,25609-74-9) → furan-2-ylmethyl methacrylate (3454-28-2)

Guidance literature:

With N-phenyl-maleimide; 2-methylbenzene-1,4-diol; 1,8-diazabicyclo[5.4.0]undec-7-ene; at 140 - 160 ℃; for 14h;

upstream raw materials:

(2-furyl)methyl alcohol

methacrylic acid methyl ester

methyl methacrylate

propyl methacrylate

Refernces

• 1、 Hadjichristidis, Nikos,Jiang, Yu. "Diels–Alder Polymer Networks with Temperature-Reversible Cross-Linking-Induced Emission". . p. 331 - 337. Retrieved 2021.