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Methanesulfonic anhydride

Base Information Edit
  • Chemical Name:Methanesulfonic anhydride
  • CAS No.:7143-01-3
  • Molecular Formula:C2H6O5S2
  • Molecular Weight:174.199
  • Hs Code.:29041000
  • European Community (EC) Number:230-442-1
  • NSC Number:65906
  • UNII:J492U7J4PB
  • DSSTox Substance ID:DTXSID70864010
  • Nikkaji Number:J24.127J
  • Wikipedia:Methanesulfonic_anhydride
  • Wikidata:Q2849892
  • Mol file:7143-01-3.mol
Methanesulfonic anhydride

Synonyms:Methanesulfonic anhydride;7143-01-3;Methanesulfonic acid, anhydride;methylsulfonyl methanesulfonate;Mesyl anhydride;Methanesulphonic anhydride;methanesulfonyl methanesulfonate;Methanesulfonic acid, 1,1'-anhydride;J492U7J4PB;MFCD00007556;NSC-65906;Mesic anhydride;methylsulfonic anhydride;methane sulfonic acid anhydride;C2H6O5S2;METHANE SULFONIC ANHYDRIDE;Ms2O;methansulfonic anhydride;di-methanesulfonyl ether;methyl sulfonic anhydride;Methane-sulfonic anhydride;(MeSO2)2O;methansulfonic acid anhydride;methylsulfonic acid anhydride;Bis(methanesulfonic)anhydride;NCIOpen2_000079;UNII-J492U7J4PB;SCHEMBL25600;methanesulfonic acid anhydride;methane-sulfonic acid anhydride;Methanesulphonic acid anhydride;(CH3SO2)2O;Methanesulfonic anhydride, 97%;SCHEMBL10811178;DTXSID70864010;CS-B0920;NSC65906;EINECS 230-442-1;NSC 65906;AKOS009104339;FS-4545;PB43340;BP-12335;FT-0656950;EN300-25979;D78221;A837175;Q-201362;Q2849892;F0001-1835

Suppliers and Price of Methanesulfonic anhydride
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Usbiological
  • Methanesulfonic Anhydride
  • 1g
  • $ 312.00
  • TRC
  • Methanesulfonic anhydride
  • 1g
  • $ 45.00
  • TRC
  • Methanesulfonic anhydride
  • 25g
  • $ 70.00
  • TRC
  • Methanesulfonic anhydride
  • 250g
  • $ 395.00
  • SynQuest Laboratories
  • Methanesulfonic anhydride 98%
  • 500 g
  • $ 308.00
  • SynQuest Laboratories
  • Methanesulfonic anhydride 98%
  • 100 g
  • $ 74.00
  • Sigma-Aldrich
  • Methanesulfonic anhydride for synthesis
  • 8180340025
  • $ 2220.00
  • Sigma-Aldrich
  • Methanesulfonic anhydride for synthesis
  • 25 g
  • $ 2127.50
  • Sigma-Aldrich
  • Methanesulfonic anhydride 97%
  • 5g
  • $ 22.50
  • Sigma-Aldrich
  • Methanesulfonic anhydride 97%
  • 25g
  • $ 73.30
Total 92 raw suppliers
Chemical Property of Methanesulfonic anhydride Edit
Chemical Property:
  • Appearance/Colour:white to light brown to grey powder, crystals 
  • Vapor Pressure:0.00386mmHg at 25°C 
  • Melting Point:64-67 °C(lit.) 
  • Refractive Index:1.469 
  • Boiling Point:289.3 °C at 760 mmHg 
  • Flash Point:128.7 °C 
  • PSA:94.27000 
  • Density:1.583 g/cm3 
  • LogP:1.08380 
  • Storage Temp.:Store at 
  • Sensitive.:Moisture Sensitive 
  • Solubility.:Soluble in organic solvents. 
  • XLogP3:-0.8
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:5
  • Rotatable Bond Count:2
  • Exact Mass:173.96566563
  • Heavy Atom Count:9
  • Complexity:227
Purity/Quality:

99% *data from raw suppliers

Methanesulfonic Anhydride *data from reagent suppliers

Safty Information:
  • Pictogram(s): Corrosive
  • Hazard Codes:
  • Statements: 14-35 
  • Safety Statements: 26-36/37/39-45 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:CS(=O)(=O)OS(=O)(=O)C
  • Uses Methanesulfonic anhydride is used to prepare methylsulfonyl esters called as mesylates. It finds application in the reaction of aromatic alkylation. It reacts with dimethylsulfoxide to get sulfoxonium complex, which is a useful oxidizing agent.
Technology Process of Methanesulfonic anhydride

There total 31 articles about Methanesulfonic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With Hexamethyldisiloxane; tin(IV) chloride; Heating;
Guidance literature:
With sulfuric acid; sulfur trioxide; dihydrogen peroxide; at 50 ℃; under 75007.5 Torr; Large scale;
Guidance literature:
With thionyl chloride; for 3h; Reflux; Inert atmosphere;
DOI:10.1021/ol302970c
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