Myristyl myristate

Base Information

• Chemical Name: Myristyl myristate
• CAS No.: 3234-85-3
• Molecular Formula: C28H56O2
• Molecular Weight: 424.751
• Hs Code.: 2915900090
• European Community (EC) Number: 221-787-9,692-044-8
• UNII: 4042ZC00DY
• DSSTox Substance ID: DTXSID5047403
• Nikkaji Number: J61.597H
• Wikidata: Q27258281
• RXCUI: 1425924
• Metabolomics Workbench ID: 3680
• Mol file: 3234-85-3.mol

Synonyms:MYRISTYL MYRISTATE;3234-85-3;Tetradecyl tetradecanoate;Ceraphyl 424;MYRISTIC ACID MYRISTYL ESTER;Tetradecanoic acid, tetradecyl ester;Cyclochem MM;Tetradecyl myristate;Myristic acid, tetradecyl ester;tetradecanyl tetradecanoate;Crodamol MM;Liponate MM;Cetiol MM;Myristyl tetradecanoate;EINECS 221-787-9;BRN 1801576;UNII-4042ZC00DY;4042ZC00DY;EC 221-787-9;WE(14:0/14:0);Schercemol MM;Alkamuls MM/M;Waxenol 810;HALLSTAR MM;MACKADERM MM;PROTACHEM MM;TEGOSOFT MM;NIKKOL MM;1-Tetradecanol, myristate;SCHEMBL44370;myristyl myristate, AldrichCPR;DTXSID5047403;MYRISTYL MYRISTATE [INCI];CHEBI:138721;MYRISTYL MYRISTATE [VANDF];tetradecanoic acid tetradecyl ester;14:0-14:0Alc;LMFA07010035;AKOS024437806;BS-49242;LS-148907;FT-0634737;E79233;A821238;W-106845;Q27258281

Chemical Property of Myristyl myristate

Chemical Property:

• Appearance/Colour: Waxy solid
• Vapor Pressure: 1.01E-08mmHg at 25°C
• Melting Point: 37-44oC
• Refractive Index: 1.452
• Boiling Point: 462.2 °C at 760 mmHg
• Flash Point: 240.8 °C
• PSA: 26.30000
• Density: 0.859 g/cm³
• LogP: 9.93180
• Storage Temp.: -20°C
• XLogP3: 13
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 26
• Exact Mass: 424.42803102
• Heavy Atom Count: 30
• Complexity: 327

Purity/Quality:

99% ^*data from raw suppliers

MyristylMyristate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC
• Uses: myristyl myristate is an occlusive skin-conditioning agent that enhances product spreadability and can reduce a product’s transparency. It is particularly useful in emulsions that have to “melt” once they come in contact with the skin. This is an ester formed by the combination of the myristyl alcohol and myristic acid fractions of coconut oil. Myristyl myristate, is one of the more used waxy esters in cosmetic formulations due to its emollient properties.

Technology Process of Myristyl myristate

There total 9 articles about Myristyl myristate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

n-tetradecanoic acid (544-63-8) → myristic acid tetradecyl ester (3234-85-3)

Guidance literature:

With hydrogen; In neat (no solvent); at 20 - 200 ℃; for 24h; under 6000.6 Torr; Autoclave; High pressure;

DOI:10.1002/adsc.201401172

Reference yield: 85.0%

1-Tetradecanol (112-72-1) + n-tetradecanoic acid (544-63-8) → myristic acid tetradecyl ester (3234-85-3)

Guidance literature:

With triphenylphosphine-sulfur trioxide adduct; In neat (no solvent); at 110 ℃; for 2h; Green chemistry;

DOI:10.1080/10426507.2020.1845681

Reference yield: 82.0%

1-Tetradecanol (112-72-1) → myristic acid tetradecyl ester (3234-85-3)

Guidance literature:

With dihydridotetrakis(triphenylphosphine)ruthenium; In 1,3,5-trimethyl-benzene; at 180 ℃; for 24h;

DOI:10.1021/jo00228a032

upstream raw materials:

1-Tetradecanol

tetradecanoyl chloride

n-tetradecanoic acid

Downstream raw materials:

1-Tetradecanol

Refernces

• 1、 Betke, Tobias,Gr?ger, Harald,Kleber, Joscha,Liese, Andreas,Schlipk?ter, Kim E.. "Fatty alcohol synthesis from fatty acids at mild temperature by subsequent enzymatic esterification and metal-catalyzed hydrogenation". . p. 7862 - 7867. Retrieved 2020/11/02.
• 2、 Zhang, Lei,Raffa, Guillaume,Nguyen, Duc Hanh,Swesi, Youssef,Corbel-Demailly, Louis,Capet, Frédéric,Trivelli, Xavier,Desset, Simon,Paul, Sébastien,Paul, Jean-Fran?ois,Fongarland, Pascal,Dumeignil, Franck,Gauvin, Régis M.. "Acceptorless dehydrogenative coupling of alcohols catalysed by ruthenium PNP complexes: Influence of catalyst structure and of hydrogen mass transfer". . p. 331 - 343. Retrieved 2016/07/06.