4-NITROPHENYL ANTHRANILATE

Base Information

• Chemical Name: 4-NITROPHENYL ANTHRANILATE
• CAS No.: 19176-60-4
• Molecular Formula: C13H10N2O4
• Molecular Weight: 258.233
• Hs Code.: 2922439000
• Mol file: 19176-60-4.mol

Synonyms:para-Nitrophenyl anthranilate;4-Nitrophenyl Anthranilate;

Chemical Property of 4-NITROPHENYL ANTHRANILATE

Chemical Property:

• Melting Point: 127-129 °C
• Refractive Index: 1.656
• Boiling Point: 467 °C at 760 mmHg
• PKA: 1.89±0.10(Predicted)
• Flash Point: 236.2 °C
• PSA: 98.14000
• Density: 1.381 g/cm³
• LogP: 3.50060
• Solubility.: almost transparency in hot Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Nitrophenyl Anthranilate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-NITROPHENYL ANTHRANILATE

There total 3 articles about 4-NITROPHENYL ANTHRANILATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + isatoic anhydride (118-48-9) → 2-Aminobenzencarbonsaeure-(4-nitrophenyl)ester (19176-60-4)

Guidance literature:

at 140 ℃; for 0.333333h;

Reference yield: 65.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + anthranil (271-58-9) → 2-Aminobenzencarbonsaeure-(4-nitrophenyl)ester (19176-60-4)

Guidance literature:

In Triethylene glycol dimethyl ether; at 216 ℃; Solvent; Temperature;

DOI:10.1021/acs.joc.8b02890

Reference yield:

→ 2-Aminobenzencarbonsaeure-(4-nitrophenyl)ester (19176-60-4)

Guidance literature:

Isatinsaeureanhydrid, p-Nitrophenol;

DOI:10.1021/ja00725a033

upstream raw materials:

4-nitro-phenol

isatoic anhydride

anthranil

Downstream raw materials:

anthranilic acid

4-nitro-phenol

2-Isothiocyanatobenzencarbonsaeure-(4-nitrophenyl)ester

p-nitrophenolate

Refernces

• 1、 Morgenstern,Schuster,Finke,Richter. "Investigations on preparation and reactivity of c-anellated derivatives of 1, 3, 4-benzotriazepines and related precursors N, N-coupled heterobicycles from cyclic hydrazine derivatives, part 12". . p. 458 - 467. Retrieved 2007/10/03.