Chlorodioctylaluminium

Base Information

• Chemical Name: Chlorodioctylaluminium
• CAS No.: 7325-26-0
• Molecular Formula: C16H34AlCl
• Molecular Weight: 288.88
• European Community (EC) Number: 230-800-7
• DSSTox Substance ID: DTXSID00223479
• Mol file: 7325-26-0.mol

Synonyms:Chlorodioctylaluminium;7325-26-0;EINECS 230-800-7;Chlorodioctylaluminum;C16H34AlCl;C16-H34-Al-Cl;DTXSID00223479

Chemical Property of Chlorodioctylaluminium

Chemical Property:

• Vapor Pressure: 14.2mmHg at 25°C
• Boiling Point: 126.4°Cat760mmHg
• Flash Point: 15.6°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.70350
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 14
• Exact Mass: 288.2164422
• Heavy Atom Count: 18
• Complexity: 134

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCC[Al](CCCCCCCC)Cl

Technology Process of Chlorodioctylaluminium

There total 2 articles about Chlorodioctylaluminium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

oct-1-ene (111-66-0,25068-25-1) + diethylaluminium chloride (96-10-6) → 3-methylenenonane (51655-64-2) + di(n-octyl)aluminum chloride (7325-26-0)

Guidance literature:

With zirconium (IV) butoxide; In toluene; at 20 ℃; for 4h;

DOI:10.1007/BF00953581

Reference yield:

→ di(n-octyl)aluminum chloride (7325-26-0)

Guidance literature:

Al-trioctyl, AlCl3 1. 30-40grad 2. 75-80grad (Ruehren);

Reference yield: 98.0%

lithium aluminium tetrahydride (16853-85-3) + oct-1-ene (111-66-0,25068-25-1) + di(n-octyl)aluminum chloride (7325-26-0) → trioctylaluminum (1070-00-4)

Guidance literature:

In further solvent(s); byproducts: LiCl; LiAlH4, oct-1-ene loaded in a vertical-type ball mill under Ar or N2; mixt. heated with agitation for 20 min at 70°C; (C8H17)2AlCl added for 0.5 h (LiAlH4:(C8H17)2AlCl:oct-1-ene=1:1:4.28); mixt. agitated for 1h at 95-100°C; cooled; ppt. filtered off; olefin removed (vac., 1 Torr) at 80-90°C; elem. anal.;

DOI:10.1023/A:1022412818827

upstream raw materials:

oct-1-ene

diethylaluminium chloride

Downstream raw materials:

di-n-octylaluminium hydride

trioctylaluminum

Refernces

• 1、 -. "Process for production of 2,6-dimethyl-1,3,6-octatriene". . . Retrieved 2008/06/13.