3-methylene-Nonane

Base Information

• Chemical Name: 3-methylene-Nonane
• CAS No.: 51655-64-2
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• Hs Code.: 2901299090
• Mol file: 51655-64-2.mol

Synonyms:3-methylene-Nonane;2-ethyl-1-octene

Chemical Property of 3-methylene-Nonane

Chemical Property:

• Melting Point: -56.93°C (estimate)
• Refractive Index: 1.4177 (estimate)
• Boiling Point: 166.82°C (estimate)
• PSA: 0.00000
• Density: 0.7631 (estimate)
• LogP: 3.92300

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-methylene-Nonane

There total 11 articles about 3-methylene-Nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

oct-1-ene (111-66-0,25068-25-1) + diethylaluminium chloride (96-10-6) → 3-methylenenonane (51655-64-2) + di(n-octyl)aluminum chloride (7325-26-0)

Guidance literature:

With zirconium (IV) butoxide; In toluene; at 20 ℃; for 4h;

DOI:10.1007/BF00953581

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + diethylmagnesium (557-18-6) → 3-methylenenonane (51655-64-2) + 3-methyl-nonane (5911-04-6)

Guidance literature:

With zirconocene dichloride; water; Product distribution; multistep reaction;

DOI:10.1007/BF01167793

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + ethylmagnesium bromide (925-90-6) → decane (124-18-5) + 3-methylenenonane (51655-64-2) + 3-methyl-nonane (5911-04-6)

Guidance literature:

With zirconocene dichloride; water; Product distribution; multistep reaction;

DOI:10.1007/BF01167793

upstream raw materials:

ethene

n-octyne

oct-1-ene

diethylmagnesium

Refernces

• 1、 Julia, M.,Marazano, C.. "BIOMIMETIC METHYL TRANSFER TO OLEFINS". . p. 3717 - 3724. Retrieved 2007/10/02.
• 2、 Dzhemilev, U. M.,Ibragimov, A. G.,Vostrikova, O. S.,Tolstikov, G. A.,Zelenova, L. M.. "NEW METHOD OF β-ALKYLATION OF α-OLEFINS USING DIALKYLALUMINUM CHLORIDE WITH CATALYTIC AMOUNTS OF Ti, Zr, AND Hf COMPLEXES". . p. 281 - 284. Retrieved 2007/10/02.