Trioxidane

Base Information

• Chemical Name: Trioxidane
• CAS No.: 14699-99-1
• Molecular Formula: H2O3
• Molecular Weight: 50.0141
• DSSTox Substance ID: DTXSID60932994
• Nikkaji Number: J1.680.850D
• Wikipedia: Trioxidane
• Wikidata: Q417642,Q27110056
• RXCUI: 1310514
• Mol file: 14699-99-1.mol

Synonyms:trioxidane;epoxy alcohol;ketoalcohol;oxoalcohol;Lactoperoxidase;Dihydroxy ether;HOOOH;Horseradish peroxidase;Horse radish peroxidase;Myeloperoxidase, human pmn;UNII-JQZ6YM58U5;UNII-2TQ44G23HV;CHEBI:46736;DTXSID60932994;EINECS 232-668-6;14699-99-1;EC 1.11.1.7;E.C. 1.11.1.7;Q417642;Q27110056

Chemical Property of Trioxidane

Chemical Property:

• PSA: 49.69000
• LogP: -0.05100
• XLogP3: -0.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 50.000393922
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: OOO

Technology Process of Trioxidane

There total 16 articles about Trioxidane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C8H11O3PolSi + water (7732-18-5) → trioxidane (14699-99-1)

Guidance literature:

With methytrioxorhenium(VII); at -30 ℃; for 3h; polystyrene bead

DOI:10.1002/anie.201504084

Reference yield: 45.0%

ozone (10028-15-6) + diphenyl hydrazine (122-66-7) → trioxidane (14699-99-1)

Guidance literature:

In acetic acid methyl ester; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in methyl acetate at -78°C;

DOI:10.1021/ja036801u

Reference yield: 45.0%

ozone (10028-15-6) + diphenyl hydrazine (122-66-7) → trioxidane (14699-99-1) + water (7732-18-5) + dihydrogen peroxide (7722-84-1)

Guidance literature:

In [⁽²⁾H₆]acetone; byproducts: PhN(O)NPh; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in acetone-d6 at -60°C; monitoring by NMR;

DOI:10.1021/ja036801u

upstream raw materials:

Triethylgerman

ozone

hydroxyl

hydroperoxyl radical

Refernces

• 1、 Ghormley, J. A.. "". . p. 3539 - 3540. Retrieved 1963.
• 2、 Nyffeler, Paul T.,Boyle, Nicholas A.,Eltepu, Laxman,Wong, Chi-Huey,Eschenmoser, Albert,Lerner, Richard A.,Wentworth Jr., Paul. "Dihydrogen trioxide (HOOOH) is generated during the thermal reaction between hydrogen peroxide and ozone". . p. 4656 - 4659. Retrieved 2004.
• 3、 Levanov, Alexander V.,Sakharov, Dmitri V.,Dashkova, Anna V.,Antipenko, Ewald E.,Lunin, Valeri V.. "Synthesis of hydrogen polyoxides H2O4 and H 2O3 and their characterization by raman spectroscopy". . p. 5144 - 5150. Retrieved 2011.