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CAS No.: | 14699-99-1 |
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Name: | Hydrogen trioxide(6CI,7CI,8CI,9CI) |
Article Data: | 18 |
Molecular Structure: | |
Formula: | H2O3 |
Molecular Weight: | 50.0141 |
Synonyms: | Dihydrogentrioxide; Hydrogen oxide (H2O3); Hydrogen sesquioxide (H2O3); Hydrogensuperoxide (H2O3) |
PSA: | 49.69000 |
LogP: | -0.05100 |
Conditions | Yield |
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With methytrioxorhenium(VII) at -30℃; for 3h; polystyrene bead; | 100% |
1,2-Dimethylhydrazine
ozone
A
trioxidane
B
water
C
dihydrogen peroxide
Conditions | Yield |
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In [(2)H6]acetone byproducts: 1,2-dimethyldiazene, 1,2-dimethyldiazene-N-oxide, nitromethane; ozonation od 1,2-dimethylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in acetone-d6 at -78°C; monitoring by GC/MS and NMR; | A 45% B n/a C 55% |
Conditions | Yield |
---|---|
In acetic acid methyl ester ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in methyl acetate at -78°C; | 45% |
ozone
diphenyl hydrazine
A
trioxidane
B
water
C
dihydrogen peroxide
Conditions | Yield |
---|---|
In [(2)H6]acetone byproducts: PhN(O)NPh; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in acetone-d6 at -60°C; monitoring by NMR; | A 45% B n/a C n/a |
In further solvent(s) byproducts: 1,2-diphenyldiazene-N-oxide, 1,2-diphenyldiazene; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in tert-butyl methyl ether at -78°C; | A 30% B n/a C 10% |
Conditions | Yield |
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In further solvent(s) react. germanium compd. with ozone at -78°C in t-butyl methyl ether; not isolated, detected by NMR; | |
In [(2)H6]acetone react. germanium compd. with ozone at -78°C in acetone-d6; not isolated, detected by NMR; | |
In acetic acid methyl ester react. germanium compd. with ozone at -78°C in methyl acetate; not isolated, detected by NMR; |
Conditions | Yield |
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rate constant;; | |
In neat (no solvent) | |
rate constant;; |
ozone
trioxidane
Conditions | Yield |
---|---|
With cumene In [(2)H6]acetone byproducts: C6H5C(CH3)(CH2); ozonization at -40°C with ozone-oxygen or O3-N2 mixt. in acetone-d6 or methyl acetate ort-butyl methel ether; not isolated; monitored by NMR; | |
With triphenylmethane In [(2)H6]acetone byproducts: (C6H5)3COOOH; ozonization at -60°C with ozone-oxygen or O3-N2 mixt. in acetone-d6 or methyl acetate ort-butyl methel ether; | 0% |
Conditions | Yield |
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With oxygen In water passage of a stream of ozone/oxygen gas through a soln. of aq. H2O2 ca.96% w/w, generated either by vacuum distillation of commercially available HOOH or pure HOOH generated by reduction of O2 in (D6)acetone or (D10)THF at -78°C; not isolated, detected by NMR-spectroscopy; |
Conditions | Yield |
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In gas MS;; |
Conditions | Yield |
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In water byproducts: HO2; other Radiation; acidic with O2 satd. water was treated with electron beam of high intensity at 23°C; yield depending on the pH;; | |
In water byproducts: HO2; other Radiation; acidic with O2 satd. water was treated with electron beam of high intensity at 23°C; yield depending on the pH;; |