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14699-99-1

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Basic Information
CAS No.: 14699-99-1
Name: Hydrogen trioxide(6CI,7CI,8CI,9CI)
Article Data: 18
Molecular Structure:
Molecular Structure of 14699-99-1 (Hydrogen trioxide(6CI,7CI,8CI,9CI))
Formula: H2O3
Molecular Weight: 50.0141
Synonyms: Dihydrogentrioxide; Hydrogen oxide (H2O3); Hydrogen sesquioxide (H2O3); Hydrogensuperoxide (H2O3)
PSA: 49.69000
LogP: -0.05100
Synthetic route

C8H11O3PolSi

14699-99-1

trioxidane

Conditions
ConditionsYield
With methytrioxorhenium(VII) at -30℃; for 3h; polystyrene bead;100%
540-73-8

1,2-Dimethylhydrazine

A

14699-99-1

trioxidane

B

7732-18-5

water

C

7722-84-1

dihydrogen peroxide

Conditions
ConditionsYield
In [(2)H6]acetone byproducts: 1,2-dimethyldiazene, 1,2-dimethyldiazene-N-oxide, nitromethane; ozonation od 1,2-dimethylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in acetone-d6 at -78°C; monitoring by GC/MS and NMR;A 45%
B n/a
C 55%
122-66-7

diphenyl hydrazine

14699-99-1

trioxidane

Conditions
ConditionsYield
In acetic acid methyl ester ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in methyl acetate at -78°C;45%
122-66-7

diphenyl hydrazine

A

14699-99-1

trioxidane

B

7732-18-5

water

C

7722-84-1

dihydrogen peroxide

Conditions
ConditionsYield
In [(2)H6]acetone byproducts: PhN(O)NPh; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in acetone-d6 at -60°C; monitoring by NMR;A 45%
B n/a
C n/a
In further solvent(s) byproducts: 1,2-diphenyldiazene-N-oxide, 1,2-diphenyldiazene; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in tert-butyl methyl ether at -78°C;A 30%
B n/a
C 10%
1188-14-3

Triethylgerman

A

14699-99-1

trioxidane

B

122554-29-4

Et3GeOOOH

Conditions
ConditionsYield
In further solvent(s) react. germanium compd. with ozone at -78°C in t-butyl methyl ether; not isolated, detected by NMR;
In [(2)H6]acetone react. germanium compd. with ozone at -78°C in acetone-d6; not isolated, detected by NMR;
In acetic acid methyl ester react. germanium compd. with ozone at -78°C in methyl acetate; not isolated, detected by NMR;
3352-57-6

hydroxyl

7782-44-7

hydroperoxyl radical

14699-99-1

trioxidane

Conditions
ConditionsYield
rate constant;;
In neat (no solvent)
rate constant;;
14699-99-1

trioxidane

Conditions
ConditionsYield
With cumene In [(2)H6]acetone byproducts: C6H5C(CH3)(CH2); ozonization at -40°C with ozone-oxygen or O3-N2 mixt. in acetone-d6 or methyl acetate ort-butyl methel ether; not isolated; monitored by NMR;
With triphenylmethane In [(2)H6]acetone byproducts: (C6H5)3COOOH; ozonization at -60°C with ozone-oxygen or O3-N2 mixt. in acetone-d6 or methyl acetate ort-butyl methel ether;0%
7722-84-1

dihydrogen peroxide

14699-99-1

trioxidane

Conditions
ConditionsYield
With oxygen In water passage of a stream of ozone/oxygen gas through a soln. of aq. H2O2 ca.96% w/w, generated either by vacuum distillation of commercially available HOOH or pure HOOH generated by reduction of O2 in (D6)acetone or (D10)THF at -78°C; not isolated, detected by NMR-spectroscopy;
1333-74-0

hydrogen

14699-99-1

trioxidane

Conditions
ConditionsYield
In gas MS;;
14699-99-1

trioxidane

Conditions
ConditionsYield
In water byproducts: HO2; other Radiation; acidic with O2 satd. water was treated with electron beam of high intensity at 23°C; yield depending on the pH;;
In water byproducts: HO2; other Radiation; acidic with O2 satd. water was treated with electron beam of high intensity at 23°C; yield depending on the pH;;
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