Methane, trichloronitroso-

Base Information

• Chemical Name: Methane, trichloronitroso-
• CAS No.: 3711-49-7
• Molecular Formula: CCl3NO
• Molecular Weight: 148.376
• DSSTox Substance ID: DTXSID80190610
• Nikkaji Number: J41.735A
• Wikipedia: Trichloronitrosomethane
• Wikidata: Q83063005
• Mol file: 3711-49-7.mol

Synonyms:Methane, trichloronitroso-;Chloroform, nitroso-;Trichloronitrosomethane;TL 358;trichloronitroso-methane;3711-49-7;CCl3NO;C-Cl3-N-O;SCHEMBL4924282;SCHEMBL7746277;DTXSID80190610;TL-358;LS-90433

Chemical Property of Methane, trichloronitroso-

Chemical Property:

• Vapor Pressure: 118mmHg at 25°C
• Boiling Point: 74.8°Cat760mmHg
• Flash Point: 15.6°C
• PSA: 29.43000
• Density: 1.78g/cm³
• LogP: 2.08050
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 146.904547
• Heavy Atom Count: 6
• Complexity: 56.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(N=O)(Cl)(Cl)Cl

Technology Process of Methane, trichloronitroso-

There total 12 articles about Methane, trichloronitroso- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

nitrodichloroacetyl chloride (24482-74-4) → trichloronitrosomethane (3711-49-7)

Guidance literature:

With aluminium trichloride; In hexane; at 20 - 30 ℃;

DOI:10.1007/BF00953106

Reference yield:

chloropicrin (76-06-2) → dichloroformoxime (1794-86-1) + N-Methylhydroxylamine (593-77-1) + trichloronitrosomethane (3711-49-7) + methylamine (74-89-5)

Guidance literature:

Bei der elektrolytischen Reduktion entstehen je nach den Bedingungen wechselnde Menge;

Reference yield:

tetrachloromethane (56-23-5) → trichloromethyl radical (3170-80-7) + trichloronitrosomethane (3711-49-7)

Guidance literature:

With nitric oxide anion; at 26.9 ℃; under 0.2 Torr; Mechanism; dissociative electron transfer;

DOI:10.1021/ja00186a006

upstream raw materials:

chloropicrin

2,2,2-trichloro-N-hydroxy-acetamide

tetrachloromethane

chloroform

Downstream raw materials:

dichloroformoxime

chloropicrin

methylamine

2-chloroformyl-5-isopropyl-3,6-dihydro-1,2-oxazine

Refernces

• 1、 Masanet, J.,Caralp, F.,Jemi-Alade, A. A.,Lightfood, P. D.,Lesclaux, R.,Rayez, M. T.. "Kinetics and Thermochemistry of the Reaction CCl3 + NO + M CCl3NO + M". . p. 3237 - 3244. Retrieved 1993.
• 2、 Rinden, Elizabeth,Maricq, M. Matti,Grabowski, Joseph J.. "Gas-Phase Ion-Molecule Reactions of the Nitric Oxide Anion". . p. 1203 - 1210. Retrieved 2007/10/02.