1-Chloro-diethylcarbamoyl-1-propen-2-yl dimethyl phosphate

Base Information

• Chemical Name: 1-Chloro-diethylcarbamoyl-1-propen-2-yl dimethyl phosphate
• CAS No.: 297-99-4
• Deprecated CAS: 13170-92-8
• Molecular Formula: C₁₀H₁₉ClNO₅P
• Molecular Weight: 299.691
• UNII: 54VR7A0BQD
• DSSTox Substance ID: DTXSID5058357
• Nikkaji Number: J437.687K,J3.767B
• Wikidata: Q27261240
• Mol file: 297-99-4.mol

Synonyms:(E)-Phosphamidon;trans-Phosphamidon;Phosphamidon, (E)-;ML 97;297-99-4;1-Chloro-diethylcarbamoyl-1-propen-2-yl dimethyl phosphate;ENT 25,515;OR 1191;UNII-54VR7A0BQD;C10H19ClNO5P;54VR7A0BQD;Fosfamidon [Dutch];Phosphoric acid, 2-chloro-3-(diethylamino)-1-methyl-3-oxo-1-propenyl dimethyl ester, (E)-;Caswell No. 661;Fosfamidone [Italian];Phosphamidon 85 WSC;2-Chloro-2-diethylcarbamoyl-1-methylvinyl dimethyl phosphate;Dimethyl 2-chloro-2-diethylcarbamoyl-methyl vinyl phosphate;Foszfamidon (Hungarian);[(E)-3-chloro-4-(diethylamino)-4-oxobut-2-en-2-yl] dimethyl phosphate;Phosophamidon;CCRIS 516;Phosphamidon [ANSI:BSI:ISO];HSDB 1754;EINECS 236-116-5;EPA Pesticide Chemical Code 018201;Phosphamidon;(Famfos);Dimethyl phosphate of 2-chloro-N,N-diethyl-3-hydroxycrotonamide;AI3-25515;N,N-Diethyl 2-chloro-3-dimethylphosphate crotonamide;2-Chloro-2-diethylcarbamyl-1-methylvinyl-dimethyl phosphate;dimercron;2-Chloro-N,N-diethyl-3-hydroxycrotonamide dimethyl phosphate;C10-H19-Cl-N-O5-P;E-Phosphamidon;Phosphamidon 8;2-Chloro-3-(diethylamino)-1-methyl-3-oxo-1-propenyl dimethyl phosphate;2-Chloro-N,N-diethyl-3-hydroxycrotonamide ester with dimethyl phosphate;(2-Chloor-3-diethylamino-1-methyl-3-oxo-prop-1-en-yl)-dimethyl-fosfaat [Dutch];(2-Chlor-3-diaethylamino-1-methyl-3-oxo-prop-1-en-yl)-dimethyl-phosphat [German];(2-Cloro-3-dietilamino-1-metil-3-oxo-prop-1-en-il)-dimetil-fosfato [Italian];O,O-Dimethyl-O-(1-methyl-2-chlor-2-N,N-diaethyl-carbamoyl)-vinyl-phosphat [German];Phosphate de dimethyle et de (2-chloro-2-diethylcarbamoyl-1-methyl-vinyle) [French];Phosphamidon (isomer);Dimethyl-(diethylamido-1-chlorocrotonyl)-phosphate;Dimethyl-(diethylamido-1- chlorocrotonyl)-phosphate;PHOSPHAMIDON, TRANS-;PHOSPHAMIDON, E ISOMER;SCHEMBL3675777;Dimethyl phosphate ester with 2-chloro-N,N-diethyl-3-hydroxycrotonamide;DTXSID5058357;Dimethyl phosphate ester with 2-chloro-N,N-diethyl-3-hydroxycrotonamide (8CI);Phosphoric acid 2-chloro-3-(diethylamino)-1-methyl-3-oxo-1-propen-1-yl dimethyl ester;phosphoric acid dimethyl ester, ester with 2-chloro-N,N-diethyl-3-hydroxycrotonamide;RGCLLPNLLBQHPF-CMDGGOBGSA-N;LS-751;1ST20656;LS-107537;Phosphamidon, PESTANAL(R), analytical standard;dimethyl diethylamido-1-chloroc rotonyl (2) phosphate;Q27261240;2-c hloro-2-diethyl carbamyl-1-methyl vinyl dimethyl-phosphate;2-chloro-2-diethyl carbamyl-1-methyl vinyl dimethyl-phosphate;dimethyl-2-chloro-2-diethylcarbamoyl-1-methylvinyl phosphate;(E)-2-CHLORO-2-DIETHYLCARBAMOYL-1-METHYLVINYL DIMETHYL PHOSPHATE;2-Chloro-N,N-diethyl-3-hydroxycrotonamide ester of dimethyl phosphat e;2-Chloro-N,N-diethyl-3-hydroxycrotonamide ester of dimethyl phosphate;dimethyl 2-chloro-3-(diethylamino)-1-methyl-3-oxo-1-propenylphosphorate;O,O-dimethyl-O-(2-chloro-2-(N,N-diethylcarbamoyl)-1-methylvinyl)phosphate;(1E)-2-Chloro-3-(diethylamino)-1-methyl-3-oxo-1-propenyl dimethyl phosphate #;(1Z)-2-chloro-3-(diethylamino)-1-methyl-3-oxoprop-1-en-1-yl dimethyl phosphate;Phosphoric acid 2-chloro-3-(diethylamino)-1- methyl-3-oxo-1-propenyl dimethyl ester;Phosphoric acid 2-chloro-3-(diethylamino)-1-methyl-3-oxo-1-propenyl dimethyl ester;phosphoric acid Chloro-3-(diethylamino)-1-methyl-3-oxo-1-propenyl dimethy l ester;phosphoric acid Chloro-3-(diethylamino)-1-methyl-3-oxo-1-propenyl dimethyl ester;Phosphoric acid, dimethyl ester, ester with 2-chloro-N-N-diethyl-3-hydroxycrotonamide;PHOSPHORIC ACID, (1E)-2-CHLORO-3-(DIETHYLAMINO)-1-METHYL-3-OXO-1-PROPEN-1-YL DIMETHYL ESTER

Chemical Property of 1-Chloro-diethylcarbamoyl-1-propen-2-yl dimethyl phosphate

Chemical Property:

• Melting Point: -45 °C
• Boiling Point: 356°Cat760mmHg
• PKA: -1.28±0.70(Predicted)
• Flash Point: 169.1°C
• PSA: 74.88000
• Density: 1.219g/cm³
• LogP: 2.74260
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 7
• Exact Mass: 299.0689374
• Heavy Atom Count: 18
• Complexity: 359

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: Poison by ingestion. When heated to decomposition it emits toxic fumes of Cl−, NOx"> −, NOx, and POx." target="_blank">Poison by ingestion. When heated to decomposition it emits toxic fumes of Cl−, NOx

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=O)C(=C(C)OP(=O)(OC)OC)Cl
• Isomeric SMILES: CCN(CC)C(=O)/C(=C(/C)\OP(=O)(OC)OC)/Cl

Technology Process of 1-Chloro-diethylcarbamoyl-1-propen-2-yl dimethyl phosphate

There total 3 articles about 1-Chloro-diethylcarbamoyl-1-propen-2-yl dimethyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2-dichloro-acetoacetic acid diethylamide (16695-57-1) + phosphorous acid trimethyl ester (121-45-9) → dimecron (297-99-4,13171-21-6,23783-98-4)

Guidance literature:

With chlorobenzene;

Reference yield:

N,N-diethyl-3-oxobutanamide (2235-46-3) → dimecron (297-99-4,13171-21-6,23783-98-4)

Guidance literature:

Multi-step reaction with 2 steps

1: SO₂Cl₂

2: chlorobenzene

With sulfuryl dichloride; In chlorobenzene;

DOI:10.1002/hlca.19610440621

Reference yield:

→ dimecron (297-99-4,13171-21-6,23783-98-4)

Guidance literature:

Trimethylphosphit, N,N-Diethyldichloracetoacetamid;

upstream raw materials:

2,2-dichloro-acetoacetic acid diethylamide

phosphorous acid trimethyl ester

N,N-diethyl-3-oxobutanamide