BICYCLO(3.3.0)OCTANE

Base Information

• Chemical Name: BICYCLO(3.3.0)OCTANE
• CAS No.: 694-72-4
• Molecular Formula: C8H14
• Molecular Weight: 110.199
• Mol file: 694-72-4.mol

Synonyms:Bicyclo(3.3.0)octane;

Chemical Property of BICYCLO(3.3.0)OCTANE

Chemical Property:

• Melting Point: -30 °C
• Refractive Index: 1.48
• Boiling Point: 140.5 °C at 760 mmHg
• Flash Point: 19.4 °C
• Density: 0.896 g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BICYCLO(3.3.0)OCTANE

There total 21 articles about BICYCLO(3.3.0)OCTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

Z-1-iodocyclooct-4-ene (103620-47-9) → cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) + bicyclo[3.3.0]octane (694-72-4)

Guidance literature:

With lithium triethylborohydride; In tetrahydrofuran; for 72h; Ambient temperature;

DOI:10.1021/jo00197a036

Reference yield: 38.0%

1,3-cyclooctadiene (3806-59-5) → cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) + bicyclo[3.3.0]octane (694-72-4) + (3aS,6aS)-1,2,3,3a,4,6a-Hexahydro-pentalene (930-99-4)

Guidance literature:

With hydrogen; potassium; magnesium oxide; at 249.9 ℃;

Reference yield: 7.0%

Z-1-iodocyclooct-4-ene (103620-47-9) → cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) + bicyclo[3.3.0]octane (694-72-4) + 2-iodobicyclo<3.3.0>octane (92285-04-6)

Guidance literature:

With lithium triethylborohydride; In tetrahydrofuran; for 217h; Ambient temperature;

DOI:10.1021/jo00197a036

upstream raw materials:

Cyclooctan

1,3-cyclooctadiene

dihydropentalene

Z-1-iodocyclooct-4-ene

Downstream raw materials:

naphthalene

2-cyclohexylnaphthalene

Refernces

• 1、 Taubmann, Sandra,Denner, Christine E.,Alt, Helmut G.. "Catalytic dehydrogenation of cyclooctane with titanium, zirconium and hafnium metallocene complexes". scheme or table. p. 2005 - 2019. Retrieved 2009/09/26.
• 2、 Kupfer, Rene,Brinker, Udo H.. "Carbenes in Constrained Systems, 3. Solid-State Photolysis of Cycloheptane- and Cyclooctanespirodiazirine within Cyclodextrins and Zeolites". . p. 1721 - 1726. Retrieved 2007/10/03.