Diallyldibutylstannane

Base Information

• Chemical Name: Diallyldibutylstannane
• CAS No.: 15336-98-8
• Molecular Formula: C14H28Sn
• Molecular Weight: 315.086
• Hs Code.: 2931900090
• European Community (EC) Number: 239-368-4
• NSC Number: 203241
• UNII: C7D5C4JMG2
• DSSTox Substance ID: DTXSID10165316
• Mol file: 15336-98-8.mol

Synonyms:DIALLYLDIBUTYLTIN;15336-98-8;Diallyldibutylstannane;dibutyl-bis(prop-2-enyl)stannane;Diallyldi-n-butyltin;EINECS 239-368-4;NSC-203241;Diallydi-n-butyltin;NSC203241;Tin, diallyldibutyl-;C7D5C4JMG2;C14-H28-Sn;Dibutyldi-2-propen-1-ylstannane;Stannane, dibutyldi-2-propenyl-;AMY7001;DTXSID10165316;dibutylbis(prop-2-en-1-yl)stannane;MFCD00014944;Stannane, dibutyldi-2-propen-1-yl-;AKOS025293684;GS-6214;NSC 203241;FT-0769134;H10466

Chemical Property of Diallyldibutylstannane

Chemical Property:

• Vapor Pressure: 0.00339mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.500
• Boiling Point: 291.5 °C at 760 mmHg
• Flash Point: 133.5 °C
• PSA: 0.00000
• Density: 1,099 g/cm3
• LogP: 5.40740
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 316.121303
• Heavy Atom Count: 15
• Complexity: 152

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diallyldibutyltin ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CC=C)CC=C
• Uses: It have application in chemical research.

Technology Process of Diallyldibutylstannane

There total 10 articles about Diallyldibutylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

dibutyltin chloride (683-18-1) + allyl bromide (106-95-6) → diallyldibutyltin (15336-98-8)

Guidance literature:

With ammonium chloride; zinc; In cyclohexane; water; appropriate alkyltin chloride is added to cyclohexane/H2O mixt. with excess of zinc powder, appropriate allyl bromide is added dropwise under stirring within 5 min, mixt. is stirred for 30 min; extn. (petroleum ether), separated org. layer is washed (aq. NaCl), drying (MgSO4), solvent is removed, distn.;

DOI:10.1021/om00015a025

Reference yield: 55.0%

C8H18Li2Sn + allyl bromide (106-95-6) → diallyldibutyltin (15336-98-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃;

Reference yield: 52.0%

dibutyltin chloride (683-18-1) + allylmagnesium bromide (2622-05-1) → diallyldibutyltin (15336-98-8)

Guidance literature:

In diethyl ether;

DOI:10.1021/ja01513a053

upstream raw materials:

dibutyltin chloride

allylmagnesium bromide

allyl bromide

Trichlorbutylstannan

Downstream raw materials:

2-allyl-2-(4-nitrophenyl)oxirane

4-phenyl-4-trimethylsiloxy-1-pentene

2-phenylpent-4-en-2-ol

1-allyl-1-cyclohexanol

Refernces

• 1、 -. "METHOD FOR PRODUCING 14 GROUP METAL LITHIUM COMPOUND". . . Retrieved 2016/10/31.
• 2、 Cunningham, Anthony,Mokal-Parekh, Vijaya,Wilson, Claire,Woodward, Simon. "On the use of mixtures of organotin species for catalytic enantioselective ketone allylation - A detective story". . p. 741 - 748. Retrieved 2007/10/03.