1-Butanamine, N-(3-phenylpropylidene)-

Base Information

• Chemical Name: 1-Butanamine, N-(3-phenylpropylidene)-
• CAS No.: 90496-14-3
• Molecular Formula: C13H19N
• Molecular Weight: 189.301
• Mol file: 90496-14-3.mol

Synonyms:

Chemical Property of 1-Butanamine, N-(3-phenylpropylidene)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Butanamine, N-(3-phenylpropylidene)-

There total 5 articles about 1-Butanamine, N-(3-phenylpropylidene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-((E)-3-phenylallylidene)butan-1-amine → 3-Phenyl-1-propanol (122-97-4) + phenylpropane (103-65-1) + N-(3-Phenyl-propyliden)-butylamin (90496-14-3) + PPC4 (92111-13-2) + C12H17N

Guidance literature:

With isopropyl alcohol; at 82 ℃; for 3h; Reagent/catalyst; Inert atmosphere;

DOI:10.1016/j.catcom.2021.106361

Reference yield:

3-Phenyl-1-propanol (122-97-4) + N-butylamine (109-73-9,85404-21-3) → 3-phenyl-propionaldehyde (104-53-0) + N‐butyl‐3‐phenylpropanamide (10264-11-6) + N-(3-Phenyl-propyliden)-butylamin (90496-14-3)

Guidance literature:

With 9-azabicyclo<3.3.1>nonane-N-oxyl; oxygen; tris[(2-pyridylmethyl)amine]; copper(l) chloride; In tetrahydrofuran; at 20 ℃; for 1h; under 760.051 Torr;

DOI:10.1021/jacs.6b03931

Reference yield:

3-phenyl-propionaldehyde (104-53-0) + N-butylamine (109-73-9,85404-21-3) → N-(3-Phenyl-propyliden)-butylamin (90496-14-3)

Guidance literature:

With zirconium(IV) tetraisopropoxide; In methanol; at 20 ℃; for 4h; Inert atmosphere;

DOI:10.2174/1570180812666141215215120

upstream raw materials:

N-butylamine

dihydrocinnamonitrile

3-phenyl-propionaldehyde

3-Phenyl-1-propanol

Downstream raw materials:

PPC₄

Butyl-(1-phenethyl-3-phenyl-propyl)-amine

1-(n-Butylamino)-1,3-diphenylpropan

N-butyl-(1-methyl-3-phenyl)propylamine

Refernces

• 1、 Gao, Xinlong,Wang, Pan,Wang, Qingqing,Chen, Jingting,Lei, Aiwen. "Electrochemical oxidative annulation of amines and aldehydes or ketones to synthesize polysubstituted pyrroles". supporting information. p. 4941 - 4945. Retrieved 2019/09/30.
• 2、 Pieri, Cyril,Brunel, Jean Michel. "First efficient two-step/one-pot zirconium (IV)isopropoxide-mediated reductive amination of carbonyl compounds". . p. 448 - 456. Retrieved 2015/06/22.