chlorodiiodomethane

Base Information

• Chemical Name: chlorodiiodomethane
• CAS No.: 638-73-3
• Molecular Formula: CH Cl I2
• Molecular Weight: 302.281
• Hs Code.: 2903799090
• Mol file: 638-73-3.mol

Synonyms:Chlorodiiodomethane;Diiodochloromethane

Chemical Property of chlorodiiodomethane

Chemical Property:

• Vapor Pressure: 0.736mmHg at 25°C
• Melting Point: -4°C
• Boiling Point: 190.8°Cat760mmHg
• Flash Point: 69.2°C
• PSA: 0.00000
• Density: 3.2g/cm³
• LogP: 2.37880
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)

Purity/Quality:

NLT 98% ^*data from raw suppliers

Diiodochloromethane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Diiodochloromethane is a potentially toxic disinfection byproducts generated at water treatment plants in USA.

Technology Process of chlorodiiodomethane

There total 2 articles about chlorodiiodomethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

iodoform (75-47-8) → diiodomethane (75-11-6) + dichloroiodomethane (594-04-7) + chlorodiiodomethane (638-73-3)

Guidance literature:

With mercury dichloride; at 130 ℃; for 2h; Title compound not separated from byproducts;

DOI:10.1016/S0043-1354(00)00079-8

Reference yield: 25.0%

chlorodibromomethane (124-48-1) → bromochloroiodomethane (34970-00-8) + chlorodiiodomethane (638-73-3)

Guidance literature:

With 18-crown-6 ether; sodium methylate; sodium iodide; In methanol; water; for 96h; Title compound not separated from byproducts;

DOI:10.1016/S0043-1354(00)00079-8

Reference yield: 78.0%

chlorodiiodomethane (638-73-3) + (2E)-3-phenyl-2-propen-1-ol (4407-36-7) → ((1S,2R,3S)-2-chloro-3-phenylcyclopropyl)methanol (1433964-20-5)

Guidance literature:

chlorodiiodomethane; With diethylzinc; In dichloromethane; at -78 ℃; for 0.166667h; Inert atmosphere;

(2E)-3-phenyl-2-propen-1-ol; With (4R,5R)-2-butyl-N⁴,N⁴,N⁵,N⁵-tetramethyl-1,3,2-dioxaborolane-4,5-dicarboxamide; In dichloromethane; at -40 ℃; for 16h; Temperature; Concentration; enantioselective reaction; Inert atmosphere; Darkness;

DOI:10.1002/chem.201202528

upstream raw materials:

iodoform

chlorodibromomethane

Downstream raw materials:

(2-chlorocyclopropyl)benzene

(2-chlorocyclopropyl)benzene

C₁₅H₁₂ClI

p-(trans-2-Chlorocyclopropyl)toluene

Refernces