Pentalene, octahydro-1-iodo-

Base Information

• Chemical Name: Pentalene, octahydro-1-iodo-
• CAS No.: 92285-04-6
• Molecular Formula: C8H13I
• Molecular Weight: 236.096
• Mol file: 92285-04-6.mol

Synonyms:

Chemical Property of Pentalene, octahydro-1-iodo-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pentalene, octahydro-1-iodo-

There total 3 articles about Pentalene, octahydro-1-iodo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.1%

Z-1-iodocyclooct-4-ene (103620-47-9) + methyllithium (917-54-4) → cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) + bicyclo[3.3.0]oct-2-ene (5549-09-7) + cis-octahydro-pentalene (1755-05-1) + 2-methylbicyclo<3.3.0>octane (32273-77-1) + 5-methylcyclo-octene (15840-67-2) + 2-iodo-cis-bicyclo<3.3.0>octane (92285-04-6,93953-50-5)

Guidance literature:

With copper(l) iodide; In tetrahydrofuran; at 0 ℃; for 0.25h; Product distribution; Mechanism; other 5-substituted 1-cyclooctenes and substituted 6-iodo-1-hexenes; var. times, solvents, addition of p-DNB, Cu(I) salts and radicals scavangers;

DOI:10.1021/jo00229a023

Reference yield: 22.0%

Z-1-iodocyclooct-4-ene (103620-47-9) → cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) + cis-octahydro-pentalene (1755-05-1) + 2-iodo-cis-bicyclo<3.3.0>octane (92285-04-6)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 49h; Product distribution; Mechanism; var. cyclooctene derivatives, other conditions;

DOI:10.1021/jo00369a009

Reference yield: 7.0%

Z-1-iodocyclooct-4-ene (103620-47-9) → cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) + bicyclo[3.3.0]octane (694-72-4) + 2-iodobicyclo<3.3.0>octane (92285-04-6)

Guidance literature:

With lithium triethylborohydride; In tetrahydrofuran; for 217h; Ambient temperature;

DOI:10.1021/jo00197a036

upstream raw materials:

Z-1-iodocyclooct-4-ene

methyllithium

Refernces

• 1、 Ashby, E. C.,Coleman, David. "Evidence for Single Electron Transfer in the Reactions of Lithium Dimethylcuprate with Alkyl Halides". . p. 4554 - 4565. Retrieved 2007/10/02.