Hexylazanium;chloride

Base Information

• Chemical Name: Hexylazanium;chloride
• CAS No.: 142-81-4
• Molecular Formula: C6H16ClN
• Molecular Weight: 137.653
• Hs Code.: 29251995
• Mol file: 142-81-4.mol

Synonyms:hexylazanium;chloride

Chemical Property of Hexylazanium;chloride

Chemical Property:

• Appearance/Colour: Colourless to yellow liquid; Fishy aroma
• Vapor Pressure: 9.12mmHg at 25°C
• Melting Point: 221.0 to 225.0 °C
• Boiling Point: 131.8°C at 760 mmHg
• Flash Point: 8.9°C
• PSA: 26.02000
• Density: 0.77 g/cm3
• LogP: 3.02770
• Water Solubility.: almost transparency
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 137.0971272
• Heavy Atom Count: 8
• Complexity: 27.4

Purity/Quality:

98% ^*data from raw suppliers

Hexylamine Hydrochloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC[NH3+].[Cl-]

Technology Process of Hexylazanium;chloride

There total 19 articles about Hexylazanium;chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-hexyl-2-azabicyclo[2.2.1]hept-5-ene (126424-16-6) → 1-hexylamine hydrochloride (142-81-4)

Guidance literature:

copper(II) sulfate; In ethanol; at 70 ℃; for 5h;

DOI:10.1021/jo00295a002

Reference yield: 97.0%

1-nitrohexane (646-14-0) → 1-hexylamine hydrochloride (142-81-4)

Guidance literature:

1-nitrohexane; With iron(III)-acetylacetonate; hydrazine hydrate; In methanol; at 150 ℃; for 0.0333333h; Microwave irradiation;

With hydrogenchloride; In water; ethyl acetate; chemoselective reaction;

DOI:10.1021/jo400556g

Reference yield: 93.0%

hexanenitrile (628-73-9) → 1-hexylamine hydrochloride (142-81-4)

Guidance literature:

hexanenitrile; With ammonium hydroxide; hydrogen; nano-dicobalt phosphide on hydrotalcite; In isopropyl alcohol; at 130 ℃; for 1h; under 30003 Torr; Autoclave;

With hydrogenchloride; In 1,4-dioxane;

DOI:10.1039/d0sc00247j

upstream raw materials:

Caproamide

2-chloro-3-hexynylamine hydrochloride

2-hexyl-2-azabicyclo[2.2.1]hept-5-ene

Hexyl-phosphorimidic acid triethyl ester

Downstream raw materials:

hexanal

4-(hexylimino-methyl)-5-hydroxymethyl-2-methyl-pyridin-3-ol

N-hexylcarbamic acid ethyl ester

hexan-1-amine

Refernces

• 1、 -. "Method for preparing amine compound by reducing amide compound". Paragraph 0247-0249. . Retrieved 2021/02/10.
• 2、 Guo, Chenjun,Zhang, Fangcao,Yu, Chong,Luo, Yunjie. "Reduction of Amides to Amines with Pinacolborane Catalyzed by Heterogeneous Lanthanum Catalyst La(CH2C6H4NMe2- o)3@SBA-15". . p. 13122 - 13135. Retrieved 2021/08/31.