Terbium(III)chloride

Base Information

• Chemical Name: Terbium(III)chloride
• CAS No.: 10042-88-3
• Molecular Formula: Cl3Tb
• Molecular Weight: 265.284
• UNII: 804HI855F8
• Nikkaji Number: J134.291F
• Mol file: 10042-88-3.mol

Synonyms:Terbium(III)chloride;TERBIUM CHLORIDE [INCI];GFISHBQNVWAVFU-UHFFFAOYSA-K;AMY22319;AKOS024256103

Chemical Property of Terbium(III)chloride

Chemical Property:

• Appearance/Colour: off-white pwdr.
• Melting Point: 588 °C(lit.)
• PSA: 0.00000
• Density: 4.35 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 263.83191
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Tb+3]

Technology Process of Terbium(III)chloride

There total 28 articles about Terbium(III)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.6%

terbium ammonium chloride → terbium(III) chloride (10042-88-3)

Guidance literature:

In neat (no solvent, solid phase); byproducts: NH4Cl; Tb-contg. compd. was heated slowly (4 h) to 630°C in flowing helium; chem anal.;

DOI:10.1007/BF02758695

Reference yield:

terbium(III, IV) oxide + ammonium chloride → terbium(III) chloride (10042-88-3)

Guidance literature:

In solid;

DOI:10.1149/1.2050043

Reference yield:

terbium(III) oxide + ammonium chloride → terbium(III) chloride (10042-88-3)

Guidance literature:

Ar atmosphere; molar ratio NH4Cl/Tb2O3 6:1;

DOI:10.1016/0022-4596(89)90032-7

upstream raw materials:

terbium(III) chloride hydrate

chlorine

aluminium

hydrogenchloride

Refernces

• 1、 Kamarzin,Osadchaya,Sokolov,Trushnikova,Zubareva,Saprykin,Troitskii. "Preparation of metallic terbium and terbium hydride". . p. 874 - 876. Retrieved 2000.
• 2、 Jin,Tsutsumi,Deguchi,Machida,Adachi. "Luminescence property of the terbium bipyridyl complex incorporated in silica matrix by a sol-gel method". . p. L195-L197. Retrieved 1995.
• 3、 Yang, Jun,Zhang, Cuimiao,Wang, Lili,Hou, Zhiyao,Huang, Shanshan,Lian, Hongzhou,Lin, Jun. "Hydrothermal synthesis and luminescent properties of LuBO3: Tb3+ microflowers". . p. 2672 - 2680. Retrieved 2008.
• 4、 Olejak-Chodan, Monika,Lasocha, Wieslaw,Eick, Harry A.. "X-RAY POWDER DIFFRACTION STUDY OF THE CHLORIDE-BROMIDE SYSTEMS OF TRIVALENT GADOLINIUM, TERBIUM, AND YTTERBIUM.". . p. 259 - 267. Retrieved 1988.
• 5、 Mitra, Samiran,Uebach, Jochen,Seifert, Hans J.. "". . p. 484 - 489. Retrieved 1995.
• 6、 An, Bao-Li,Gong, Meng-Lian,Cheah, Kok-Wai,Wong, Wai-Kwok,Zhang, Ji-Ming. "Synthesis, structure and photoluminescence of novel lanthanide (Tb(III), Gd(III)) complexes with 6-diphenylamine carbonyl 2-pyridine carboxylate". . p. 326 - 332. Retrieved 2004.
• 7、 Tanner, Peter A.,Wang, Jiwei. "Energy transfer from Gd3+ to Tb3+ in solution". . p. 335 - 338. Retrieved 2008.
• 8、 Bettonville, S.,Goudiakas, J.,Fuger, J.. "Thermodynamics of lanthanide elements. III. Molar enthalpies of formation of Tb3+(aq), Ho3+(aq), Yb3+(aq), Yb2+(aq), TbBr3(cr), HoBr3(cr), and YbBr3(cr) at 298.15 K". . p. 595 - 604. Retrieved 1987.
• 9、 Velchuri, Radha,Kumar, B. Vijaya,Devi, V. Rama,Prasad,Prakash, D. Jaya,Vithal. "Preparation and characterization of rare earth orthoborates, LnBO 3 (Ln = Tb, La, Pr, Nd, Sm, Eu, Gd, Dy, Y) and LaBO3:Gd, Tb, Eu by metathesis reaction: ESR of LaBO3:Gd and luminescence of LaBO3:Tb, Eu". . p. 1219 - 1226. Retrieved 2011/07/09.
• 10、 Ambrozini, B.,Dametto, P. R.,Ionashiro, M.. "Synthesis, characterization and thermal behaviour of solid-state tartrates of heavy trivalent lanthanides and yttrium(III)". . p. 867 - 871. Retrieved 2011/10/31.