Hydrogen isocyanide

Base Information

• Chemical Name: Hydrogen isocyanide
• CAS No.: 6914-07-4
• Molecular Formula: CHN
• Molecular Weight: 27.0256
• Wikipedia: Hydrogen_isocyanide
• Wikidata: Q1107746
• Metabolomics Workbench ID: 55501
• Mol file: 6914-07-4.mol

Synonyms:hydrogen isocyanide;isocyanic acid

Chemical Property of Hydrogen isocyanide

Chemical Property:

• Boiling Point: 25.7°Cat760mmHg
• Flash Point: °C
• Density: 0.695g/cm³
• XLogP3: 0.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 27.010899036
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[NH+]

Technology Process of Hydrogen isocyanide

There total 25 articles about Hydrogen isocyanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

ammonia (7664-41-7) + toluene (108-88-3,15644-74-3,16713-13-6) → hydrogen isocyanide (74-90-8,6914-07-4)

Guidance literature:

hydrogen faujasite; In gas; byproducts: H2; 1000 K, 1 atm, 1.5 h on stream;

DOI:10.1039/c39800000097

Reference yield:

BBr3*H(1+)*CN(1-)=BBr3*HCN + water (7732-18-5) → boron trioxide + hydrogen isocyanide (74-90-8,6914-07-4) + hydrogen bromide (10035-10-6,12258-64-9)

Guidance literature:

Reference yield:

BBr3*Ag(1+)*CN(1-)=BBr3*AgCN → hydrogen isocyanide (74-90-8,6914-07-4) + hydrogen bromide (10035-10-6,12258-64-9)

Guidance literature:

With water; alcohol;

upstream raw materials:

methyl azide

nitromethane

oxygen

nitrogen(II) oxide

Downstream raw materials:

HCN⁽¹⁺⁾

hydrogen cyanide

carbon nitride

trifluoromethylium

Refernces

• 1、 Macdonald, R. Glen. "Rotational and vibrational state distributions of HNC(0 v21 0) from the hot H atom reaction: H + (CN)2 → HNC + CN". . p. 10202 - 10211. Retrieved 2000.
• 2、 Decker, Brian K.,Macdonald, R. Glen. "Channeling of products in the hot atom reaction H + (CN)2 → HCN/HNC + CN and in the reaction of CN with CH3SH". . p. 6817 - 6825. Retrieved 2007/10/03.