Iodine isocyanate

Base Information

• Chemical Name: Iodine isocyanate
• CAS No.: 3607-48-5
• Molecular Formula: CNI
• Molecular Weight: 168.922
• DSSTox Substance ID: DTXSID30189655
• Mol file: 3607-48-5.mol

Synonyms:Iodine isocyanate;3607-48-5;INCO;DTXSID30189655;NPURPEXKKDAKIH-UHFFFAOYSA-N

Chemical Property of Iodine isocyanate

Chemical Property:

• Vapor Pressure: 21.1mmHg at 25°C
• Boiling Point: 117.1°Cat760mmHg
• Flash Point: 24.6°C
• Density: 2.51g/cm³
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 168.90246
• Heavy Atom Count: 4
• Complexity: 46

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=NI)=O

Technology Process of Iodine isocyanate

There total 5 articles about Iodine isocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iodine (7553-56-2,12190-71-5,8031-47-8) + silver cyanate (3315-16-0) → iodine isocyanate (3607-48-5)

Guidance literature:

In tetrahydrofuran; excess of I2, stirring -30°C in dark;

DOI:10.1021/ac60242a025

Reference yield:

silver cyanate (3315-16-0) → iodine isocyanate (3607-48-5)

Guidance literature:

With iodine; passing of 1% I2 in He over AgNCO suspended on glass wool (433 K, total pressure 30 Torr);

DOI:10.1063/1.456510

Reference yield:

silver cyanate (3315-16-0) + Iodine monochloride (7790-99-0) → iodine isocyanate (3607-48-5) + silver(I) chloride

Guidance literature:

In neat (no solvent); ICl gas was passed over AgNCO at room temp.;

DOI:10.1021/ic030158v

upstream raw materials:

diethyl ether

iodine

silver cyanate

Iodine monochloride

Downstream raw materials:

carbon dioxide

ammonia

iodine

iodic acid

Refernces

• 1、 Yimin, Li,Zhimin, Qiao,Qiao, Sun,Jincai, Zhao,Haiyang, Li,Dianxun, Wang. "Preparations of Pure ISeCN, ISCN, and INCO". . p. 8446 - 8448. Retrieved 2008/10/09.