Bis(2-methylpropyl)(prop-2-en-1-yl)alumane

Base Information

• Chemical Name: Bis(2-methylpropyl)(prop-2-en-1-yl)alumane
• CAS No.: 95978-76-0
• Molecular Formula: C11H23Al
• Molecular Weight: 182.285
• DSSTox Substance ID: DTXSID00587169
• Wikidata: Q82479503
• Mol file: 95978-76-0.mol

Synonyms:95978-76-0;Bis(2-methylpropyl)(prop-2-en-1-yl)alumane;DTXSID00587169

Chemical Property of Bis(2-methylpropyl)(prop-2-en-1-yl)alumane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 182.1615141
• Heavy Atom Count: 12
• Complexity: 106

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C[Al](CC=C)CC(C)C

Technology Process of Bis(2-methylpropyl)(prop-2-en-1-yl)alumane

There total 1 articles about Bis(2-methylpropyl)(prop-2-en-1-yl)alumane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diisobutylaluminum chloride (1779-25-5) + allylmagnesium bromide (1730-25-2) → allyldiisobutylaluminium (95978-76-0)

Guidance literature:

In diethyl ether; at 0 - 20 ℃; for 11h;

Reference yield: 86.0%

3-phenyl-propionaldehyde (104-53-0) + allyldiisobutylaluminium (95978-76-0) → 1-phenylhex-5-en-3-ol (60340-28-5)

Guidance literature:

With tin(II) trifluoromethanesulfonate; (S)-1-methyl-2-<(piperidin-1-yl)-methyl>pyrrolidine; In dichloromethane; at -78 ℃; for 1h;

DOI:10.1246/bcsj.60.3697

Reference yield: 78.0%

allyldiisobutylaluminium (95978-76-0) + cyclohexanecarbaldehyde (2043-61-0) → 1-cyclohexyl-3-buten-1-ol (69036-26-6)

Guidance literature:

With tin(II) trifluoromethanesulfonate; (S)-1-methyl-2-<(piperidin-1-yl)-methyl>pyrrolidine; In dichloromethane; at -78 ℃; for 1h;

DOI:10.1246/bcsj.60.3697

upstream raw materials:

diisobutylaluminum chloride

allylmagnesium bromide

Downstream raw materials:

(1E,3R)-1-phenyl-1,5-hexadien-3-ol

trans-(S)-1-phenyl-1,5-hexadien-3-ol

1-phenylhex-5-en-3-ol

(S)-1-(p-tolyl)but-3-en-1-ol

Refernces