(-)-Menthyl chloride

Base Information Edit

Chemical Name:(-)-Menthyl chloride
CAS No.:16052-42-9
Molecular Formula:C10H19Cl
Molecular Weight:174.714
Hs Code.:2903890090
European Community (EC) Number:240-200-7
NSC Number:55430
Nikkaji Number:J129.476H
Mol file:16052-42-9.mol

Synonyms:16052-42-9;(-)-Menthyl chloride;(1s,2r,4r)-2-chloro-1-isopropyl-4-methylcyclohexane;(-)-3-Chloro-p-menthane;Cyclohexane, 2-chloro-4-methyl-1-(1-methylethyl)-, (1S,2R,4R)-;(1S,2R,4R)-2-chloro-4-methyl-1-propan-2-ylcyclohexane;C10H19Cl;(1S,2R,4R)-2-chloro-4-methyl-1-(propan-2-yl)cyclohexane;NSC55430;(1R,2S,5R)-(-)-Menthyl chloride;(--)menthyl chloride;(?)-Menthyl chloride;(-)-Menthyl chloride, 98%;SCHEMBL10001723;Cyclohexane, 2-chloro-4-methyl-1-(1-methylethyl)-, (1S-(1alpha,2beta,4beta))-;MFCD00001481;NSC-55430;AS-71351;BB 0260390;CS-0328614;M0834;T71870;Cyclohexane, [1S-(1.alpha.,2.beta.,4.beta.)]-;J-009730;(1R)-(-)-Menthyl chloride, (1S,2R,4R)-2-Chloro-1-isopropyl-1-methylcyclohexane, [1S-(1alpha,2beta,4beta)]-2-Chloro-4-methyl-1-(methylethyl)cyclohexane

Suppliers and Price of (-)-Menthyl chloride

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Chloro-4-methyl-1-(1-methylethyl)-Cyclohexane
500mg
$ 55.00

TRC
2-Chloro-4-methyl-1-(1-methylethyl)-Cyclohexane
250mg
$ 45.00

TRC
2-Chloro-4-methyl-1-(1-methylethyl)-Cyclohexane
1g
$ 90.00

TCI Chemical
(-)-Menthyl Chloride >98.0%(GC)
1g
$ 163.00

Sigma-Aldrich
(?)-Menthyl chloride 98%
1g
$ 60.50

Sigma-Aldrich
(?)-Menthyl chloride 98%
10g
$ 286.00

Matrix Scientific
(1R,2S,5R)-(-)-Menthyl chloride
1g
$ 142.00

Crysdot
(1S,2R,4R)-2-Chloro-1-isopropyl-4-methylcyclohexane 95+%
10g
$ 491.00

Chem-Impex
(-)-Menthylchloride,≥98%(GC) ≥98%(GC)
25ML
$ 71.05

American Custom Chemicals Corporation
(-)-MENTHYL CHLORIDE 95.00%
1G
$ 733.43

Total 25 raw suppliers

Chemical Property of (-)-Menthyl chloride Edit

Chemical Property:

Appearance/Colour:colorless liquid
Vapor Pressure:0.209mmHg at 25°C
Melting Point:-20-16.5 °C
Refractive Index:n20/D 1.464
Boiling Point:216.1 °C at 760 mmHg
Flash Point:78.9 °C
PSA：0.00000
Density:0.92 g/cm³
LogP:3.68600
XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:174.1175283
Heavy Atom Count:11
Complexity:120

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Chloro-4-methyl-1-(1-methylethyl)-Cyclohexane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC1CCC(C(C1)Cl)C(C)C
Isomeric SMILES:C[C@@H]1CC[C@H]([C@@H](C1)Cl)C(C)C
Uses 2-Chloro-4-methyl-1-(1-methylethyl)-Cyclohexane is a useful building block for organic synthesis.

Technology Process of (-)-Menthyl chloride

There total 23 articles about (-)-Menthyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 2216-51-5
(-)-menthol

: 16052-42-9
(1R,2S,5R)-menthyl chloride

Guidance literature:: With hydrogenchloride; zinc(II) chloride; In water; at 0 - 20 ℃; for 48h; Schlenk technique;
DOI:10.1021/acs.orglett.1c01222

Reference yield: 99.0%

: 61548-81-0
(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl methanesulfonate

: 16052-42-9
(1R,2S,5R)-menthyl chloride

Guidance literature:: With chloro-trimethyl-silane; iron(III)-acetylacetonate; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/adsc.201000740