(Methoxymethoxy)cyclododecane

Base Information

• Chemical Name: (Methoxymethoxy)cyclododecane
• CAS No.: 42604-12-6
• Molecular Formula: C14H28O2
• Molecular Weight: 228.375
• Hs Code.: 2909209000
• European Community (EC) Number: 255-908-1
• DSSTox Substance ID: DTXSID4068408
• Nikkaji Number: J309.959H
• Wikidata: Q81995136
• Mol file: 42604-12-6.mol

Synonyms:(Methoxymethoxy)cyclododecane;methoxymethoxycyclododecane;42604-12-6;Boisambrene;Cyclododecane, (methoxymethoxy)-;Formaldehyde cyclodecyl methyl acetal;Methoxycyclodocecyloxymethane;Formaldehyde cyclododecyl methyl acetal;EINECS 255-908-1;BRN 2432409;SCHEMBL3504567;DTXSID4068408;Formaldehyde methyl cyclododecyl acetal;LS-55958

Chemical Property of (Methoxymethoxy)cyclododecane

Chemical Property:

• Vapor Pressure: 0.00686mmHg at 25°C
• Refractive Index: 1.4780 (estimate)
• Boiling Point: 279.3°Cat760mmHg
• Flash Point: 85.9°C
• PSA: 18.46000
• Density: 0.89g/cm³
• LogP: 4.28020
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 228.208930132
• Heavy Atom Count: 16
• Complexity: 136

Purity/Quality:

98.5% ^*data from raw suppliers

(METHOXYMETHOXY)CYCLODODECANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCOC1CCCCCCCCCCC1

Technology Process of (Methoxymethoxy)cyclododecane

There total 3 articles about (Methoxymethoxy)cyclododecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Dimethoxymethane (109-87-5) + cyclododecanol (1724-39-6) → cyclododecyl methoxymethyl ether (42604-12-6)

Guidance literature:

With toluene-4-sulfonic acid; lithium bromide; for 1h; Ambient temperature;

DOI:10.1055/s-1985-31112

Reference yield: 92.0%

cyclododecanol (1724-39-6) + chloromethyl methyl ether (107-30-2) → cyclododecyl methoxymethyl ether (42604-12-6)

Guidance literature:

cyclododecanol; With sodium hydride; In N,N-dimethyl-formamide; benzene; at 20 ℃; for 2h;

chloromethyl methyl ether; In N,N-dimethyl-formamide; benzene; at 20 ℃; for 16h; Further stages.;

DOI:10.1039/b202411j

Reference yield:

→ cyclododecyl methoxymethyl ether (42604-12-6)

Guidance literature:

Formaldehyd, Cyclododecanol;

upstream raw materials:

Dimethoxymethane

cyclododecanol

chloromethyl methyl ether

Downstream raw materials:

cyclododecanol

cyclododecane

Refernces

• 1、 Gras, Jean-Louis,Kong Win Chang, You-Yan,Guerin, Anne. "Lithium Bromide-Assisted Protection of Primary and Secondary Alcohols as Methoxymethyl Ethers using Dimethoxymethane". . p. 74 - 75. Retrieved 2007/10/02.