9,9'-Bianthracene

Base Information

• Chemical Name: 9,9'-Bianthracene
• CAS No.: 1055-23-8
• Molecular Formula: C28H18
• Molecular Weight: 354.451
• Hs Code.: 29029090
• NSC Number: 179353
• DSSTox Substance ID: DTXSID9074438
• Nikkaji Number: J80.057K
• Wikidata: Q72443343
• Mol file: 1055-23-8.mol

Synonyms:9,9'-Bianthracene;1055-23-8;9,9'-Bianthryl;9-anthracen-9-ylanthracene;9,9'-Bianthracenyl;9-(9-Anthryl)anthracene;9,9-bianthryl;9,9'-Bianthranyl;9,9'-Dianthracene;9,9/'-Bianthracene;C28H18;AI3-19380;10-(anthracen-10-yl)anthracene;NSC179353;9,9'-Dianthracenyl;9,9\'-Bianthracene;9,9 inverted exclamation mark -bianthracene;DTXSID9074438;BAA05523;AB6106;MFCD00130216;AKOS015895994;AC-5801;NSC 179353;NSC-179353;SB66557;AS-15951;LS-43549;B4095;FT-0621604;c1(c2ccccc2cc3c1cccc3)c4c5ccccc5cc6ccccc46;A801254;J-519483

Chemical Property of 9,9'-Bianthracene

Chemical Property:

• Appearance/Colour: light yellow flaky crystal
• Melting Point: >300 °C
• Refractive Index: 1.8430 (estimate)
• Boiling Point: 523.787 °C at 760 mmHg
• Flash Point: 268.249 °C
• PSA: 0.00000
• Density: 1.217 g/cm³
• LogP: 7.96640
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 8.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 354.140850574
• Heavy Atom Count: 28
• Complexity: 444

Purity/Quality:

99% ^*data from raw suppliers

9,9''-Bianthracene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=C3C=CC=CC3=C2C4=C5C=CC=CC5=CC6=CC=CC=C64
• Uses: 9,9'-Bianthracene is a useful research chemical.

Technology Process of 9,9'-Bianthracene

There total 43 articles about 9,9'-Bianthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

9,9′-dianthryl sulfoxide → 9,9'-bianthracene (1055-23-8)

Guidance literature:

In dichloromethane; Irradiation;

DOI:10.1002/anie.201306236

Reference yield: 93.0%

anthracen-9(10H)-one (90-44-8) → 9,9'-bianthracene (1055-23-8)

Guidance literature:

anthracen-9(10H)-one; With zinc(II) chloride; zinc; In tetrahydrofuran; water; at 20 ℃; for 8h;

With toluene-4-sulfonic acid; In toluene; Reflux;

Reference yield: 92.0%

10,10′-tetrahydro-9,9′-dihydroxybianthryl (4393-30-0) → 9,9'-bianthracene (1055-23-8)

Guidance literature:

With aluminium trichloride; at 20 ℃; for 0.0166667h;

DOI:10.3390/60500442

upstream raw materials:

9-Bromoanthracene

anthracene

anthracen-9(10H)-one

bianthronyl

Downstream raw materials:

9,10-dihydroanthracene

[9,9']Bianthracenyl; compound with benzene

anthracene

Refernces

• 1、 Winkler,Winkler. "". . p. 1695,1696. Retrieved 1967.
• 2、 Kang, Seokwoo,Lee, Hayoon,Park, Jongwook,Park, Sunwoo,Shim, Yeonhee. "Fine tuning of bipolar side group on dual anthracene core derivatives for highly efficient blue emitters". . . Retrieved 2020.
• 3、 Bell,Waring. "-". . p. 1579,1582. Retrieved 1949.
• 4、 Lamotte, Michel,Lapouyade, Rene,Pereyre, Josette,Joussot-Dubien, Jacques. "Photochemical reaction of anthracene in cyclohexane polycrystals dispersed in liquid nitrogen". . p. 725 - 726. Retrieved 1980.
• 5、 Rashidi-Ranjbar, Parviz,Kianmehr, Ebrahim. "Facile and fast pinacol rearrangement by AlCl3 in the solid state". . p. 442 - 447. Retrieved 2001.
• 6、 Natarajan, Palani,Schmittel, Michael. "Photoluminescence, redox properties, and electrogenerated chemiluminescence of twisted 9,9′-bianthryls". . p. 10383 - 10394. Retrieved 2013.
• 7、 Stein, Thomas,Lang, Heinrich. "Monomere Kupfer(I)-Alkyle mit β-Wasserstoffatomen und Kupfer(I)-Aryle mit kondensierten Aromaten; die Festkoerperstruktur von [(η5-C5H4SiMe3)2Ti(CCSiMe3)2]CunC4H9". . p. 142 - 149. Retrieved 2002.
• 8、 Pham, Phuoc Dien,Legoupy, Stéphanie. "Organotin reagents supported on ionic liquid: highly efficient catalytic free radical reduction of alkyl halides". . p. 3780 - 3782. Retrieved 2009.
• 9、 Berke, Carl M.,Streitwieser, Andrew. "REACTIONS OF ANTHRACENE ANIONS WITH BERYLLIUM CHLORIDE". . p. 123 - 134. Retrieved 1980.
• 10、 Catalan, Javier,Reichardt, Christian. "Analysis of the solvatochromism of 9,9′-biaryl compounds using a pure solvent dipolarity scale". . p. 4726 - 4734. Retrieved 2012.