Bi-linderone

Base Information

• Chemical Name: Bi-linderone
• CAS No.: 1227375-09-8
• Molecular Formula: C34H32O10
• Molecular Weight: 600.61188
• Mol file: 1227375-09-8.mol

Synonyms:Bi-linderone

Chemical Property of Bi-linderone

Chemical Property:

• PSA: 123.66000
• LogP: 3.91340

Purity/Quality:

98% ^*data from raw suppliers

Bi-linderone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bi-linderone

There total 25 articles about Bi-linderone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

Methyllinderone (3984-73-4) → linderaspirone A (1235126-53-0,1235126-46-1) + C34H32O10 + bilinderone (1227375-09-8) + epi-bi-linderone (1227375-09-8)

Guidance literature:

In hexane; acetone; at 20 ℃; for 8h; Inert atmosphere; Irradiation;

DOI:10.1021/ol200418e

Reference yield: 58.0%

Methyllinderone (3984-73-4) → linderaspirone A (1235126-53-0,1235126-46-1) + C34H32O10 + bilinderone (1227375-09-8) + epi-bi-linderone (1227375-09-8)

Guidance literature:

In hexane; acetone; at 20 ℃; for 8h; Inert atmosphere; Irradiation;

DOI:10.1021/ol200418e

Reference yield: 54.0%

Methyllinderone (3984-73-4) → (+/-)-bi-linderone (1227375-09-8) + (+/-)-linderaspirone A (1235126-46-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In toluene; at 80 ℃; for 20h;

DOI:10.1016/j.tetlet.2011.03.081

upstream raw materials:

Methyllinderone

(E)-3,4-dimethoxy-5-((E)-2-oxo-4-phenylbut-3-en-1-ylidene)furan-2(5H)-one

(E)-4-hydroxy-2,3-dimethoxy-4-(2-oxo-4-phenylbut-3-en-1-yl)cyclobut-2-enone

Linderone

Refernces

• 1、 Tan, Haibo,Zheng, Chao,Liu, Zheng,Wang, David Zhigang. "Biomimetic total syntheses of linderaspirone A and bi-linderone and revisions of their biosynthetic pathways". . p. 2192 - 2195. Retrieved 2011/06/25.