(1-cyclopropylethyl)benzene

Base Information

• Chemical Name: (1-cyclopropylethyl)benzene
• CAS No.: 16510-30-8
• Molecular Formula: C11H14
• Molecular Weight: 146.232
• Mol file: 16510-30-8.mol

Synonyms:

Chemical Property of (1-cyclopropylethyl)benzene

Chemical Property:

• Vapor Pressure: 0.517mmHg at 25°C
• Boiling Point: 198°Cat760mmHg
• Flash Point: 64.5°C
• Density: 0.982g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-cyclopropylethyl)benzene

There total 22 articles about (1-cyclopropylethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

α-cyclopropylstyrene (825-76-3) → α-cyclopropyl ethyl benzene (16510-30-8)

Guidance literature:

With iron(III) chloride; lithium aluminium tetrahydride; hydrogen; In tetrahydrofuran; at 20 ℃; for 20h; under 7500.75 Torr; Inert atmosphere; Sealed tube;

DOI:10.1039/c4gc02368d

Reference yield: 65.0%

H(1+)*Mn(CO)5(1-)=HMn(CO)5 (100334-15-4,18129-11-8) + α-cyclopropylstyrene (825-76-3) → Mn2(CO)9(η1-HCOCH2CH2CHC(Ph)CH3) + Mn(CO)5(C2H4CHC(CH3)C6H5) + α-cyclopropyl ethyl benzene (16510-30-8) + cis-5-Phenyl-hexen-(4)-al (132179-74-9)

Guidance literature:

In benzene-d6; react. is carried out in a 5 mm NMR tube; CPS, then benzene and bibenzyl are added to the NMR tube contg. Hg, then HMn(CO)5 is added by vacuum transfer and the tube is sealed., react. for 3.5 h, 22°C, various product ratio for various conditions; react. is monitored by NMR; Kinetics;

DOI:10.1016/0022-328X(92)83184-J

Reference yield: 29.0%

(1-cyclopropyl-1-methoxyethyl)benzene (5558-06-5) → α-cyclopropyl ethyl benzene (16510-30-8)

Guidance literature:

With N¹,N¹,N¹²,N¹²-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a:2,1'-c][1,4]diazepine-2,12-diamine; In N,N-dimethyl-formamide; for 72h; Inert atmosphere; Glovebox; UV-irradiation;

DOI:10.1002/anie.201208066

upstream raw materials:

bromobenzene

Cyclopropyl methyl ketone

α-cyclopropylstyrene

2-cyclopropyl-2-phenylpropiophenone

Downstream raw materials:

(2-methyl-butyl)-benzene

2-phenylpentane

(1-ethylpropyl)benzene

Refernces

• 1、 Hall,S.S. et al.. "-". . p. 1494 - 1498. Retrieved 1976.
• 2、 Park, Yoonsu,Kim, Sangmin,Tian, Lei,Zhong, Hongyu,Scholes, Gregory D.,Chirik, Paul J.. "Visible light enables catalytic formation of weak chemical bonds with molecular hydrogen". . p. 969 - 976. Retrieved 2021/07/25.
• 3、 Kattamuri, Padmanabha V.,West, Julian G.. "Hydrogenation of alkenes via cooperative hydrogen atom transfer". supporting information. p. 19316 - 19326. Retrieved 2020/11/13.