7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one, 12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dod ecahydro-4,9,11-trihydroxy-6-methoxy-4a,8,13,13-tetramethyl-, [2aR-(2aa,4b,4ab,6b,9a,11a,12a,12aa,12ba)]-

Base Information Edit

Chemical Name:7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one, 12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dod ecahydro-4,9,11-trihydroxy-6-methoxy-4a,8,13,13-tetramethyl-, [2aR-(2aa,4b,4ab,6b,9a,11a,12a,12aa,12ba)]-
CAS No.:183133-97-3
Molecular Formula:C30H38O10
Molecular Weight:558.626
Hs Code.:
Mol file:183133-97-3.mol

7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one, 12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dod ecahydro-4,9,11-trihydroxy-6-methoxy-4a,8,13,13-tetramethyl-, [2aR-(2aa,4b,4ab,6b,9a,11a,12a,12aa,12ba)]-

Synonyms:

Suppliers and Price of 7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one, 12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dod ecahydro-4,9,11-trihydroxy-6-methoxy-4a,8,13,13-tetramethyl-, [2aR-(2aa,4b,4ab,6b,9a,11a,12a,12aa,12ba)]-

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one, 12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dod ecahydro-4,9,11-trihydroxy-6-methoxy-4a,8,13,13-tetramethyl-, [2aR-(2aa,4b,4ab,6b,9a,11a,12a,12aa,12ba)]- Edit

Chemical Property:

Purity/Quality:: 98.5% ^*data from raw suppliers

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Technology Process of 7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one, 12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dod ecahydro-4,9,11-trihydroxy-6-methoxy-4a,8,13,13-tetramethyl-, [2aR-(2aa,4b,4ab,6b,9a,11a,12a,12aa,12ba)]-

There total 5 articles about 7,11-Methano-5H-cyclodeca[3,4]benz[1,2-b]oxet-5-one, 12b-(acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dod ecahydro-4,9,11-trihydroxy-6-methoxy-4a,8,13,13-tetramethyl-, [2aR-(2aa,4b,4ab,6b,9a,11a,12a,12aa,12ba)]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 160084-70-8
4α-acetoxy-2α-benzoyIoxy-5β,20-epoxy-1β,13α-dihydroxy-10β-methoxy-9-oxo-7β-triethylsilyloxy-11-taxene

: 183133-97-3
4α-acetoxy-2α-benzoyloxy-5β,20-epoxy-10β-methoxy-9-oxo-1β,13α,7β-trihydroxy-11-taxene

Guidance literature:: 4α-acetoxy-2α-benzoyIoxy-5β,20-epoxy-1β,13α-dihydroxy-10β-methoxy-9-oxo-7β-triethylsilyloxy-11-taxene; With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃;

With water; In tetrahydrofuran;

Reference yield:

: 115437-18-8
7-triethylsilyl-10-deacetylbaccatin III

: 183133-97-3
4α-acetoxy-2α-benzoyloxy-5β,20-epoxy-10β-methoxy-9-oxo-1β,13α,7β-trihydroxy-11-taxene

Guidance literature:: Multi-step reaction with 2 steps

1: lithium hexamethyldisilazane / tetrahydrofuran / 1 h / -20 - 20 °C

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

With tetrabutyl ammonium fluoride; lithium hexamethyldisilazane; In tetrahydrofuran;

Reference yield:

: 32981-86-5,172018-16-5
10-deacetylbaccatin III

: 183133-97-3
4α-acetoxy-2α-benzoyloxy-5β,20-epoxy-10β-methoxy-9-oxo-1β,13α,7β-trihydroxy-11-taxene

Guidance literature:: Multi-step reaction with 3 steps

1: 1H-imidazole / N,N-dimethyl-formamide / -20 - 0 °C

2: lithium hexamethyldisilazane / tetrahydrofuran / 1 h / -20 - 20 °C

3: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

With 1H-imidazole; tetrabutyl ammonium fluoride; lithium hexamethyldisilazane; In tetrahydrofuran; N,N-dimethyl-formamide;