CYCLOPENTADIENYL(FLUORENE)IRON HEXAFLUOROPHOSPHATE

Base Information

• Chemical Name: CYCLOPENTADIENYL(FLUORENE)IRON HEXAFLUOROPHOSPHATE
• CAS No.: 38959-35-2
• Molecular Formula: C18H14F6FeP 10*
• Molecular Weight: 432.128
• Mol file: 38959-35-2.mol

Synonyms:CYCLOPENTADIENYL(FLUORENE)IRON HEXAFLUOROPHOSPHATE;CYCLOPENTADIENYL(FLUORENE)IRON HEXAFLUOR;cyclopentadienyl(fluorene)iron(ii) hexafluorophosphate;Cyclopentadienyl(fluorene)iron(II) hexafluorophosphate 98%

Chemical Property of CYCLOPENTADIENYL(FLUORENE)IRON HEXAFLUOROPHOSPHATE

Chemical Property:

• Melting Point: 163 °C (dec.)(lit.)
• PSA: 13.59000
• LogP: 7.15570

Purity/Quality:

98% purity ^*data from raw suppliers

CYCLOPENTADIENYL(FLUORENE)IRON(II) HEXAFLUOROPHOSPHATE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Catalytic photoinitiator for radical and cationic photochemical polymerization. Reactant for: Solid-state synthesis of carbon nanostructures. Synthesis of fulvalene-bridged bimetallic compounds based on Pauson-Khand chemistry.

Technology Process of CYCLOPENTADIENYL(FLUORENE)IRON HEXAFLUOROPHOSPHATE

There total 2 articles about CYCLOPENTADIENYL(FLUORENE)IRON HEXAFLUOROPHOSPHATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

ammonium hexafluorophosphate + ferrocene (102-54-5,55404-68-7) + 9H-fluorene (86-73-7) → η-fluorene-η-cyclopentadienyliron(II) hexafluorophosphate (38959-35-2)

Guidance literature:

With aluminium trichloride; aluminium; In water; other Radiation; 0.02 mol metal addn. to arene, Fe- and Al-salts mixt. in 1,2,4-C6H3Cl3 (ratio arene:Fe:AlCl3:Al=1:2:4:3.7), homogenization (stirring), mixt. irradiation in microwave oven (850 W) for 3 min, ice addn. (AlCl3 decompn.), filtration, filtrate washing (Et2O); filtration, treating with aq. NH4-salt, ppt. filtration off through sinter, washing (i-PrOH, Et2O);

DOI:10.1039/P19950000743

Reference yield:

sodium hexaflorophosphate + {(Cp)iron(I)(fluorene)} → sodium peroxide + η-fluorene-η-cyclopentadienyliron(II) hexafluorophosphate (38959-35-2)

Guidance literature:

With oxygen; In tetrahydrofuran; addn. of O2 at -80°C under dry N2;

Reference yield: 85.0%

[Fe(η-Cp)(η-fluorene)][PF6] (38959-35-2) + phosphorous acid trimethyl ester (121-45-9) → 9H-fluorene (86-73-7) + {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6 (79105-28-5)

Guidance literature:

In acetonitrile; Electrolysis; electrolysis (-1.5 V vs. SCE, Hg cathode, N2 atmosphere, in dark, 0.2 MLiClO4, few min); solvent removal;

DOI:10.1039/c39830000768

upstream raw materials:

ferrocene

9H-fluorene

Downstream raw materials:

ferrocenecarboxaldehyde

Fe(C₅H₅)(C₅H₃(C₆H₅)2)

9H-fluorene

{(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6

Refernces

• 1、 Dabirmanesh, Qumars,Fernando, Sharon I. S.,Roberts, Roger M. G.. "Synthesis and decomplexation of (η-arene)(η-cyclopentadienyl)iron(II) hexafluorophosphates using microwave dielectric heating". . p. 743 - 750. Retrieved 2007/10/02.