{(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6

Base Information

• Chemical Name: {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6
• CAS No.: 79105-28-5
• Molecular Formula: C₁₄H₃₂FeO₉P₃*F₆P
• Molecular Weight: 638.135
• Mol file: 79105-28-5.mol

Synonyms:{(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6

Chemical Property of {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6

There total 4 articles about {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[Fe(η-Cp)(η-9,10-dihydroanthracene)][PF6] (59236-70-3) + phosphorous acid trimethyl ester (121-45-9) → 9,10-dihydroanthracene (613-31-0) + {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6 (79105-28-5)

Guidance literature:

In acetonitrile; Electrolysis; electrolysis (-1.5 V vs. SCE, Hg cathode, N2 atmosphere, in dark, 0.2 MLiClO4, few min); solvent removal;

DOI:10.1039/c39830000768

Reference yield: 85.0%

[Fe(η-Cp)(η-fluorene)][PF6] (38959-35-2) + phosphorous acid trimethyl ester (121-45-9) → 9H-fluorene (86-73-7) + {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6 (79105-28-5)

Guidance literature:

In acetonitrile; Electrolysis; electrolysis (-1.5 V vs. SCE, Hg cathode, N2 atmosphere, in dark, 0.2 MLiClO4, few min); solvent removal;

DOI:10.1039/c39830000768

Reference yield: 53.0%

η-cyclopentadienyl-η-1,2,4,5-tetramethylbenzeneiron(II) hexafluorophosphate + phosphorous acid trimethyl ester (121-45-9) → {(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6 (79105-28-5) + 1,2,4,5-tetramethylbenzene (95-93-2)

Guidance literature:

In acetonitrile; Electrolysis; electrolysis (-1.5 V vs. SCE, Hg cathode, N2 atmosphere, in dark, 0.2 MLiClO4, few min); solvent removal;

DOI:10.1039/c39830000768

upstream raw materials:

[Fe(η-Cp)(η-9,10-dihydroanthracene)][PF6]

phosphorous acid trimethyl ester

[Fe(η-Cp)(η-fluorene)][PF6]

Refernces

• 1、 Darchen, Andre. "Electron Transfer Catalysis of Arene Deco-ordination in the Cationic (η5-Cyclopentadienyl)(η6-arene)iron(II) Complexes". . p. 768 - 769. Retrieved 2007/10/02.