Phenyldimethylacetoxysilane

Base Information

• Chemical Name: Phenyldimethylacetoxysilane
• CAS No.: 17887-60-4
• Molecular Formula: C10H14O2Si
• Molecular Weight: 194.305
• Hs Code.: 2931900090
• European Community (EC) Number: 241-836-8
• DSSTox Substance ID: DTXSID70884995
• Nikkaji Number: J260.784K
• Wikidata: Q82863626
• Mol file: 17887-60-4.mol

Synonyms:Phenyldimethylacetoxysilane;17887-60-4;dimethyl(phenyl)silyl acetate;Acetoxydimethylphenylsilane;[dimethyl(phenyl)silyl] acetate;Silanol, 1,1-dimethyl-1-phenyl-, 1-acetate;Silanol, dimethylphenyl-, acetate;EINECS 241-836-8;Dimethylphenylsilanol acetate;SCHEMBL475969;DTXSID70884995;MFCD00039833;AKOS006344177;1,1-Dimethyl-1-Phenyl- 1-Acetate-Silanol;FT-0637619

Chemical Property of Phenyldimethylacetoxysilane

Chemical Property:

• Vapor Pressure: 0.00834mmHg at 25°C
• Refractive Index: 1.4907
• Boiling Point: 198.7 °C at 760 mmHg
• Flash Point: 61.6 °C
• PSA: 26.30000
• Density: 0.99 g/cm³
• LogP: 1.66180
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 194.076306220
• Heavy Atom Count: 13
• Complexity: 183

Purity/Quality:

98%,99%, ^*data from raw suppliers

PHENYLDIMETHYLACETOXYSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)O[Si](C)(C)C1=CC=CC=C1

Technology Process of Phenyldimethylacetoxysilane

There total 12 articles about Phenyldimethylacetoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

dimethyl(ethoxy)phenylsilane (1825-58-7) + acetic anhydride (108-24-7) → (acetoxy)dimethyl(phenyl)silane (17887-60-4)

Guidance literature:

With CBV₇₈₀; at 110 ℃; for 0.0833333h; Concentration; Microwave irradiation;

Reference yield: 81.1%

acetic acid (64-19-7,77671-22-8) + lithium tetrakis(dimethylphenylsilyl)mercurate(II) (57528-86-6) → Dimethylphenylsilane (766-77-8) + (acetoxy)dimethyl(phenyl)silane (17887-60-4)

Guidance literature:

In hexane; at 20 ℃; for 24h;

Reference yield: 80.0%

(Acetoxymethyl)methylphenylsilane (88811-67-0) → (acetoxy)dimethyl(phenyl)silane (17887-60-4)

Guidance literature:

at 180 ℃; for 4h;

upstream raw materials:

potassium acetate

phenyldimethylsilyl chloride

acetic acid

sodium acetate

Downstream raw materials:

Acetic acid (1R,4S)-4-(dimethyl-phenyl-silanyloxy)-cyclopent-2-enyl ester

Acetylphosphonsaeure-propylester-(dimethyl-phenyl-silylester)

1,1,3,3-tetramethyl-1,3-diphenyldisiloxane

1.3-Bis-chlormethyl-tetrakis-(dimethyl-phenyl-siloxy)-disiloxan

Refernces

• 1、 -. "Method for Producing Acyloxysilanes, Acyloxysilanes Obtained Thereby, and Use of Same". Paragraph 0131; 0167; 0168; 0169; 0170; 0171; 0172; 0173. . Retrieved 2018/03/25.
• 2、 Leigh,Boukherroub,Bradaric,Cserti,Schmeisser. "Steady state and time-resolved spectroscopic studies of the photochemistry of 1-arylsilacyclobutanes and the chemistry of 1-arylsilenes". . p. 1136 - 1147. Retrieved 2007/10/03.