Denudadione C

Base Information

• Chemical Name: Denudadione C
• CAS No.: 61240-34-4
• Molecular Formula: C₂₀H₂₀O₅
• Molecular Weight: 340.376
• Mol file: 61240-34-4.mol

Synonyms:Denudadione C;(1R,5R,6R,7R)-rel-7-(1,3-Benzodioxol-5-yl)-3-methoxy-6-methyl-5-(2-propen-1-yl)bicyclo[3.2.1]oct-3-ene-2,8-dione

Chemical Property of Denudadione C

Chemical Property:

• PSA: 61.83000
• LogP: 3.00940

Purity/Quality:

HPLC≥98% ^*data from raw suppliers

DenudadioneC 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Denudadione C

There total 2 articles about Denudadione C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

2-hydroxy-4,5-dimethoxyallylbenzene (59893-87-7) → Acetic acid (1S,2R)-2-((R)-5-allyl-1,2-dimethoxy-4-oxo-cyclohexa-2,5-dienyl)-1-benzo[1,3]dioxol-5-yl-propyl ester (89067-50-5,90082-08-9) + Acetic acid (2R,4S,5R,6R)-4-benzo[1,3]dioxol-5-yl-8,9-dimethoxy-5-methyl-11-oxo-spiro[5.5]undeca-7,9-dien-2-yl ester (89067-51-6) + (1R,5R,6R,7R)-5-Allyl-7-benzo[1,3]dioxol-5-yl-3-methoxy-6-methyl-bicyclo[3.2.1]oct-3-ene-2,8-dione (61240-34-4,64999-17-3,89104-60-9,90082-07-8,90082-09-0,112438-08-1,133319-37-6)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In acetic acid; trifluoroacetic acid; anodic oxidation;

Reference yield: 25.0%

2-hydroxy-4,5-dimethoxyallylbenzene (59893-87-7) + (Z)-5-(prop-1-en-1-yl)benzo[d][1,3]dioxole (17627-76-8) → (+/-)-futoenone (19913-01-0,20156-97-2,90318-81-3,150652-81-6) + (1R,5R,6R,7S)-5-Allyl-7-benzo[1,3]dioxol-5-yl-3-methoxy-6-methyl-bicyclo[3.2.1]oct-3-ene-2,8-dione (61240-34-4,64999-17-3,89104-60-9,90082-07-8,90082-09-0,112438-08-1,133319-37-6)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In acetic acid; trifluoroacetic acid; anodic oxidation;

upstream raw materials:

2-hydroxy-4,5-dimethoxyallylbenzene

(Z)-5-(prop-1-en-1-yl)benzo[d][1,3]dioxole

Refernces