Phenol, 2-nitro-, silver(1+) salt

Base Information

• Chemical Name: Phenol, 2-nitro-, silver(1+) salt
• CAS No.: 86255-27-8
• Molecular Formula: C6H4AgNO3
• Molecular Weight: 245.971
• Hs Code.: 2908999090
• Mol file: 86255-27-8.mol

Synonyms:Phenol, 2-nitro-, silver(1+) salt

Chemical Property of Phenol, 2-nitro-, silver(1+) salt

Chemical Property:

• PSA: 68.88000
• LogP: 2.26180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenol, 2-nitro-, silver(1+) salt

There total 2 articles about Phenol, 2-nitro-, silver(1+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

silver(II) nitrate + 2-hydroxynitrobenzene (88-75-5,78813-12-4) → silver(I) 2-nitrophenoxide (86255-27-8)

Guidance literature:

In phosphorus pentaoxide; sodium hydroxide; water;

Reference yield: 71.0%

silver nitrate + 2-hydroxynitrobenzene (88-75-5,78813-12-4) → silver(I) 2-nitrophenoxide (86255-27-8)

Guidance literature:

With (C₂H₅)3N; In ethanol; acetonitrile; standard Schlenk techniques under N2; 2-nitrophenol dissolved in EtOH, Et3N added, mixture dropwise added to AgNO3 in EtOH/CH3CN at 0°C, stirred for 2 h at 0°C; collected, washed with EtOH and petroleum ether, dried in vac.;

DOI:10.1016/j.ica.2010.05.049

Reference yield: 98.0%

tributylphosphine (998-40-3) + silver(I) 2-nitrophenoxide (86255-27-8) → (tri-n-butylphosphine)2Ag(2-nitrophenol)

Guidance literature:

In diethyl ether; standard Schlenk techniques under N2; nBu3P added to Ag-compd. (molar ratio 2:1) in Et2O at 25°C, stirred for 2 h at 25°C; filtered through a pad of Celite, all volatilies removed in vac., elem. anal.;

DOI:10.1016/j.ica.2010.05.049

upstream raw materials:

2-hydroxynitrobenzene

Downstream raw materials:

heptyl-(2-nitro-phenyl)-ether

2-nitrophenyl octyl ether

1-nitro-2-(pentyloxy)benzene

(2-nitro-phenyl)-nonyl ether

Refernces

• 1、 -. "ENZYME DETECTION/ASSAY METHOD AND SUBSTRATES". . . Retrieved 2008/06/13.