TetrabutylphosphoniuM Malonate

Base Information

• Chemical Name: TetrabutylphosphoniuM Malonate
• CAS No.: 1196086-79-9
• Molecular Formula: C₃H₂O₄*2C₁₆H₃₆P
• Molecular Weight: 620.918
• Mol file: 1196086-79-9.mol

Synonyms:TetrabutylphosphoniuM Malonate

Chemical Property of TetrabutylphosphoniuM Malonate

Chemical Property:

• Melting Point: 112-122°C
• PSA: 107.44000
• LogP: 9.28510

Purity/Quality:

99% ^*data from raw suppliers

Tetrabutylphosphonium malonate 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TetrabutylphosphoniuM Malonate

There total 1 articles about TetrabutylphosphoniuM Malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

malonic acid (141-82-2) + tetra-n-butylphosphonium hydroxide (14518-69-5) → tetra(n-butyl)phosphonium malonate (1196086-79-9)

Guidance literature:

In water; at 20 ℃; Inert atmosphere;

DOI:10.1002/ejoc.201900109

upstream raw materials:

malonic acid

tetra-n-butylphosphonium hydroxide

Refernces

• 1、 Xu, Hua-Jian,Zhao, Yong-Qiang,Zhou, Xin-Feng. "Palladium-catalyzed heck reaction of aryl chlorides under mild conditions promoted by organic ionic bases". experimental part. p. 8036 - 8041. Retrieved 2011/12/02.